polygalacturonic-acid has been researched along with triethylenediamine* in 1 studies
1 other study(ies) available for polygalacturonic-acid and triethylenediamine
Article | Year |
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Allyl deprotection of galacturonic acid derivatives: mechanistic aspects of mercuric-catalyzed prop-1-enyl acetal cleavage.
Different deallylation methods were assayed for selective deprotection of allyl galactopyranosiduronic acid derivatives. A two-step procedure using DABCO and (Ph(3)P)(3)RhCl followed by mercuric-assisted cleavage gave quantitative yields. Reaction in the presence of [(18)O]water allowed us to obtain evidence about the mechanism of prop-1-enyl cleavage. Topics: Acetals; Carbohydrate Conformation; Carbohydrates; Hexuronic Acids; Magnetic Resonance Spectroscopy; Mercury; Models, Chemical; Molecular Structure; Piperazines; Rhodium; Temperature; Water | 2007 |