piperidines and cryptopleurine

piperidines has been researched along with cryptopleurine* in 1 studies

Other Studies

1 other study(ies) available for piperidines and cryptopleurine

ArticleYear
Asymmetric total syntheses of (-)-antofine and (-)-cryptopleurine using (R)-(E)-4-(tributylstannyl)but-3-en-2-ol.
    The Journal of organic chemistry, 2004, Apr-30, Volume: 69, Issue:9

    The asymmetric total syntheses of the representative phenanthroindolizidine and phenanthroquinolizidine alkaloids, (-)-antofine and (-)-cryptopleurine, are described. An efficient synthetic pathway to the key intermediate 12, in enantiomerically pure form, was achieved by using a chiral building block (R)-9 and the Overman rearrangement with a total transfer of chirality. The problem of constructing the pyrrolidine and piperidine rings was successfully addressed, primarily by using a ring-closing metathesis reaction and a cross-metathesis reaction, respectively.

    Topics: Alkaloids; Alkylation; Animals; Butanols; Cyclization; Indoles; Molecular Structure; Organotin Compounds; Phenanthrolines; Piperidines; Pyrrolidines; Quinolizines; Stereoisomerism

2004