piperidines and benzaldehyde

piperidines has been researched along with benzaldehyde* in 1 studies

Other Studies

1 other study(ies) available for piperidines and benzaldehyde

ArticleYear
Enantioselective allyltitanations and metathesis reactions. Application to the synthesis of piperidine alkaloids (+)-sedamine and (-)-prosophylline.
    The Journal of organic chemistry, 2002, Apr-05, Volume: 67, Issue:7

    An enantioselective synthesis of the piperidine alkaloids (+)-sedamine and (-)-prosophylline is reported. The synthesis of (+)-sedamine has been achieved in 12 steps with an overall yield of 20% from benzaldehyde, and (-)-prosophylline was obtained in 15 steps with an overall yield of 9.2%, starting from D-glyceraldehyde acetonide 14. The key steps are enantioselective allyltitanation reactions and ring-closing or cross-metathesis reactions.

    Topics: Alkaloids; Benzaldehydes; Catalysis; Chemistry, Organic; Chromatography, High Pressure Liquid; Cyclization; Ethers, Cyclic; Glyceraldehyde; Magnetic Resonance Spectroscopy; Molecular Structure; Piperidines; Stereoisomerism

2002