peperomin-e and savinin

peperomin-e has been researched along with savinin* in 1 studies

Other Studies

1 other study(ies) available for peperomin-e and savinin

Article	Year
Phosphorylated cyclopropanes in the synthesis of α-alkylidene-γ-butyrolactones: total synthesis of (±)-savinin, (±)-gadain and (±)-peperomin E. Organic & biomolecular chemistry, 2016, Sep-26, Volume: 14, Issue:38 Phosphorylated cyclopropanes, generated via the Rh(ii)-catalysed intramolecular cyclopropanation of α-(diethoxyphosphoryl)acetates, have been found to be useful precursors in the synthesis of α-alkylidene-γ-butyrolactones. These cyclopropyl intermediates undergo regioselective reductive ring-opening and subsequent Horner-Wadsworth-Emmons olefination to complete the synthesis. Total syntheses of (±)-savinin and (±)-gadain, as well as the first total synthesis of (±)-peperomin E, are all described using this method. Topics: 4-Butyrolactone; Benzodioxoles; Biological Products; Catalysis; Crystallography, X-Ray; Cyclopropanes; Lignans; Models, Molecular; Phosphorylation; Rhodium; Stereoisomerism	2016

Article

Year

Phosphorylated cyclopropanes in the synthesis of α-alkylidene-γ-butyrolactones: total synthesis of (±)-savinin, (±)-gadain and (±)-peperomin E.

Organic & biomolecular chemistry, 2016, Sep-26, Volume: 14, Issue:38

Phosphorylated cyclopropanes, generated via the Rh(ii)-catalysed intramolecular cyclopropanation of α-(diethoxyphosphoryl)acetates, have been found to be useful precursors in the synthesis of α-alkylidene-γ-butyrolactones. These cyclopropyl intermediates undergo regioselective reductive ring-opening and subsequent Horner-Wadsworth-Emmons olefination to complete the synthesis. Total syntheses of (±)-savinin and (±)-gadain, as well as the first total synthesis of (±)-peperomin E, are all described using this method.

Topics: 4-Butyrolactone; Benzodioxoles; Biological Products; Catalysis; Crystallography, X-Ray; Cyclopropanes; Lignans; Models, Molecular; Phosphorylation; Rhodium; Stereoisomerism

2016