peloruside-a and dithiane

peloruside-a has been researched along with dithiane* in 1 studies

Other Studies

1 other study(ies) available for peloruside-a and dithiane

Article	Year
Total synthesis of (-)-2-epi-peloruside A. Organic letters, 2008, Dec-18, Volume: 10, Issue:24 A convergent synthesis of (-)-2-epi-peloruside A has been achieved. Highlights include implementation of multicomponent type I anion relay chemistry (ARC) to unite 2-TBS-1,3-dithiane with two epoxides to construct the eastern hemisphere, a late-stage dithiane union to secure the complete, fully functionalized carbon backbone, and Yamaguchi macrolactonization, which led to (-)-2-epi-peloruside A via an unexpected epimerization at C(2). Topics: Aldehydes; Animals; Bridged Bicyclo Compounds, Heterocyclic; Epoxy Compounds; Lactones; Porifera; Quinolizines; Sulfur Compounds	2008

Article

Year

Total synthesis of (-)-2-epi-peloruside A.

Organic letters, 2008, Dec-18, Volume: 10, Issue:24

A convergent synthesis of (-)-2-epi-peloruside A has been achieved. Highlights include implementation of multicomponent type I anion relay chemistry (ARC) to unite 2-TBS-1,3-dithiane with two epoxides to construct the eastern hemisphere, a late-stage dithiane union to secure the complete, fully functionalized carbon backbone, and Yamaguchi macrolactonization, which led to (-)-2-epi-peloruside A via an unexpected epimerization at C(2).

Topics: Aldehydes; Animals; Bridged Bicyclo Compounds, Heterocyclic; Epoxy Compounds; Lactones; Porifera; Quinolizines; Sulfur Compounds

2008