pectenotoxin-6 and dioxirane

pectenotoxin-6 has been researched along with dioxirane* in 1 studies

Other Studies

1 other study(ies) available for pectenotoxin-6 and dioxirane

Article	Year
Synthesis of the ABC fragment of the pectenotoxins. Organic letters, 2005, Jun-23, Volume: 7, Issue:13 [reaction: see text] A highly stereocontrolled synthesis of the C1-C16 ABC spiroacetal-containing fragment 5 of PTX7 (4) has been achieved. Appendage of the C ring to the AB fragment involved Wittig reaction of spiroacetal aldehyde 8 with a stabilized ylide 9 followed by displacement of allylic iodide 27 with a lithium acetylide to afford enyne 7. Fructose-derived chiral dioxirane and dihydroxylation were then used to introduce the correct functionality in the tetrahydrofuran C ring. Topics: Animals; Dinoflagellida; Epoxy Compounds; Fructose; Macrolides; Marine Toxins; Molecular Structure; Peptide Fragments; Pyrans; Spiro Compounds; Stereoisomerism	2005

Article

Year

Synthesis of the ABC fragment of the pectenotoxins.

Organic letters, 2005, Jun-23, Volume: 7, Issue:13

[reaction: see text] A highly stereocontrolled synthesis of the C1-C16 ABC spiroacetal-containing fragment 5 of PTX7 (4) has been achieved. Appendage of the C ring to the AB fragment involved Wittig reaction of spiroacetal aldehyde 8 with a stabilized ylide 9 followed by displacement of allylic iodide 27 with a lithium acetylide to afford enyne 7. Fructose-derived chiral dioxirane and dihydroxylation were then used to introduce the correct functionality in the tetrahydrofuran C ring.

Topics: Animals; Dinoflagellida; Epoxy Compounds; Fructose; Macrolides; Marine Toxins; Molecular Structure; Peptide Fragments; Pyrans; Spiro Compounds; Stereoisomerism

2005