palmyrolide-a has been researched along with citronellal* in 1 studies
1 other study(ies) available for palmyrolide-a and citronellal
Article | Year |
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Synthesis of palmyrolide A and its cis-isomer and mechanistic insight into trans-cis isomerisation of the enamide macrocycle.
Concise and protecting-group free synthesis of ent-palmyrolide A and (-)-cis-palmyrolide A were achieved starting from commercially available (S)-citronellal. The key fragment of palmyrolide A, "(5S,7S)-7-hydroxy-5,8,8-trimethylnonanamide", which makes up the most challenging part of the target molecule, was prepared in just three steps. A plausible mechanism for the trans-cis isomerization of the double bond in the macrocycle has been investigated. Topics: Acyclic Monoterpenes; Aldehydes; Isomerism; Macrolides; Monoterpenes | 2013 |