pactamycin and cyclopentenone

pactamycin has been researched along with cyclopentenone* in 1 studies

Other Studies

1 other study(ies) available for pactamycin and cyclopentenone

Article	Year
Diastereoselective synthesis of vicinal tertiary diols. Organic letters, 2013, Apr-19, Volume: 15, Issue:8 A strategy for the synthesis of differentiated vicinal tertiary diols is described. The key step is a high-yielding, diastereoselective LaCl3·2LiCl-mediated addition of a Grignard or organolithium reagent to ketone 2a. The reaction is believed to proceed via a 1,3-chelated intermediate. One of the adducts has been transformed into a functionalized cyclopentenone resembling the core structure of pactamycin. Topics: Alcohols; Catalysis; Cyclopentanes; Ketones; Molecular Structure; Pactamycin; Stereoisomerism	2013

Article

Year

Diastereoselective synthesis of vicinal tertiary diols.

Organic letters, 2013, Apr-19, Volume: 15, Issue:8

A strategy for the synthesis of differentiated vicinal tertiary diols is described. The key step is a high-yielding, diastereoselective LaCl3·2LiCl-mediated addition of a Grignard or organolithium reagent to ketone 2a. The reaction is believed to proceed via a 1,3-chelated intermediate. One of the adducts has been transformed into a functionalized cyclopentenone resembling the core structure of pactamycin.

Topics: Alcohols; Catalysis; Cyclopentanes; Ketones; Molecular Structure; Pactamycin; Stereoisomerism

2013