oxazolidine and valinol

oxazolidine has been researched along with valinol* in 1 studies

Other Studies

1 other study(ies) available for oxazolidine and valinol

Article	Year
Synthesis of highly enantioenriched chiral alpha-aminoorganotins via diastereoselective ring opening of chiral N-(arenesulfonyl) 2-tributylstannyloxazolidines. The Journal of organic chemistry, 2009, Aug-21, Volume: 74, Issue:16 trans-N-(Arenesulfonyl)-2-tributylstannyloxazolidines derived from (R)-phenylglycinol were diastereoselectively ring-opened by soft organometallic reagents in the presence of BF(3).OEt(2). Both higher order organocuprates and allyltributyltin afforded the desired products in good-to-excellent yields and high diastereoselectivities (dr up to 99/1). The stereochemical assignments of tributylstannyl-beta-aminoalcohols were firmly established from NMR data and after determination of several radiocrystallographic structures. Mechanisms were proposed in order to rationalize the observed selectivities. Topics: Ethanolamines; Glycine; Nitrogen; Organotin Compounds; Oxazoles; Propanolamines; Stereoisomerism; Substrate Specificity; Valine	2009

Article

Year

Synthesis of highly enantioenriched chiral alpha-aminoorganotins via diastereoselective ring opening of chiral N-(arenesulfonyl) 2-tributylstannyloxazolidines.

The Journal of organic chemistry, 2009, Aug-21, Volume: 74, Issue:16

trans-N-(Arenesulfonyl)-2-tributylstannyloxazolidines derived from (R)-phenylglycinol were diastereoselectively ring-opened by soft organometallic reagents in the presence of BF(3).OEt(2). Both higher order organocuprates and allyltributyltin afforded the desired products in good-to-excellent yields and high diastereoselectivities (dr up to 99/1). The stereochemical assignments of tributylstannyl-beta-aminoalcohols were firmly established from NMR data and after determination of several radiocrystallographic structures. Mechanisms were proposed in order to rationalize the observed selectivities.

Topics: Ethanolamines; Glycine; Nitrogen; Organotin Compounds; Oxazoles; Propanolamines; Stereoisomerism; Substrate Specificity; Valine

2009