oxazolidine and 2-aminopropanol

oxazolidine has been researched along with 2-aminopropanol* in 2 studies

Other Studies

2 other study(ies) available for oxazolidine and 2-aminopropanol

Article	Year
Straightforward synthesis of enantiopure (R)- and (S)-trifluoroalaninol. Organic & biomolecular chemistry, 2010, Oct-21, Volume: 8, Issue:20 Two efficient routes are reported for the synthesis of both enantiomers of trifluoroalaninol in enantiopure form. The first pathway involves a Strecker-type reaction performed from a chiral trifluoromethyloxazolidine (Fox). The second route, which is more direct, involves, as a key step, the reduction of chiral oxazolidines or imines derived from ethyl trifluoropyruvate. Topics: Oxazoles; Propanolamines; Pyruvic Acid; Stereoisomerism	2010
Synthesis of highly enantioenriched chiral alpha-aminoorganotins via diastereoselective ring opening of chiral N-(arenesulfonyl) 2-tributylstannyloxazolidines. The Journal of organic chemistry, 2009, Aug-21, Volume: 74, Issue:16 trans-N-(Arenesulfonyl)-2-tributylstannyloxazolidines derived from (R)-phenylglycinol were diastereoselectively ring-opened by soft organometallic reagents in the presence of BF(3).OEt(2). Both higher order organocuprates and allyltributyltin afforded the desired products in good-to-excellent yields and high diastereoselectivities (dr up to 99/1). The stereochemical assignments of tributylstannyl-beta-aminoalcohols were firmly established from NMR data and after determination of several radiocrystallographic structures. Mechanisms were proposed in order to rationalize the observed selectivities. Topics: Ethanolamines; Glycine; Nitrogen; Organotin Compounds; Oxazoles; Propanolamines; Stereoisomerism; Substrate Specificity; Valine	2009

Article

Year

Straightforward synthesis of enantiopure (R)- and (S)-trifluoroalaninol.

Organic & biomolecular chemistry, 2010, Oct-21, Volume: 8, Issue:20

Two efficient routes are reported for the synthesis of both enantiomers of trifluoroalaninol in enantiopure form. The first pathway involves a Strecker-type reaction performed from a chiral trifluoromethyloxazolidine (Fox). The second route, which is more direct, involves, as a key step, the reduction of chiral oxazolidines or imines derived from ethyl trifluoropyruvate.

Topics: Oxazoles; Propanolamines; Pyruvic Acid; Stereoisomerism

2010

Synthesis of highly enantioenriched chiral alpha-aminoorganotins via diastereoselective ring opening of chiral N-(arenesulfonyl) 2-tributylstannyloxazolidines.

The Journal of organic chemistry, 2009, Aug-21, Volume: 74, Issue:16

trans-N-(Arenesulfonyl)-2-tributylstannyloxazolidines derived from (R)-phenylglycinol were diastereoselectively ring-opened by soft organometallic reagents in the presence of BF(3).OEt(2). Both higher order organocuprates and allyltributyltin afforded the desired products in good-to-excellent yields and high diastereoselectivities (dr up to 99/1). The stereochemical assignments of tributylstannyl-beta-aminoalcohols were firmly established from NMR data and after determination of several radiocrystallographic structures. Mechanisms were proposed in order to rationalize the observed selectivities.

Topics: Ethanolamines; Glycine; Nitrogen; Organotin Compounds; Oxazoles; Propanolamines; Stereoisomerism; Substrate Specificity; Valine

2009