orabase and melamine

Industrial dye wastewater poses a threat to human health due to its harmful effects, and the treatment of related wastewater is receiving increasing attention. In this paper, the melamine sponge with high porosity and convenient separation was selected as matrix material, and alginate/carboxymethyl cellulose-melamine sponge composite (SA/CMC-MeS) was prepared through crosslinking strategy. Not only does the composite cleverly combined the merits of alginate and carboxymethyl cellulose, it also enhanced the adsorption performance for methylene blue (MB). The adsorption data manifested that the adsorption process of SA/CMC-MeS agreed with the Langmuir model and pseudo-second-order kinetic model, and theoretical maximum adsorption capacity was 230 mg/g (pH 8). The characterization results demonstrated that the adsorption mechanism was attributed to the electrostatic attraction between the carboxyl anions on the composite and the dye cations in solution. Importantly, SA/CMC-MeS could selectively separate MB from binary dye system and had positive anti-interference ability in the face of coexisting cations. After 5 times of cycles, the adsorption efficiency remained above 75 %. Based on these outstanding practical properties, this material has a potential to solve dye contamination.

Topics: Adsorption; Alginates; Carboxymethylcellulose Sodium; Cations; Humans; Hydrogen-Ion Concentration; Kinetics; Methylene Blue; Wastewater; Water Pollutants, Chemical

A novel carboxymethyl cellulose (CMC)-modified melamine-formaldehyde (MF) phase change capsule with excellent encapsulation was prepared by in situ polymerization. Effects of CMC on the properties of the capsules were studied by Fourier transformation infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), scanning electronic microscopy (SEM), X-ray diffractometry (XRD), and thermogravimetric analysis (TGA). The results showed that the CMC-modified capsules had an average diameter of about 50nm and good uniformity. The phase change enthalpy of the capsules was increased and the cracking ratio decreased by incorporating a suitable amount of CMC. The optimum phase change enthalpy of the nanocapsules was 83.46J/g, and their paraffin content was 63.1%. The heat resistance of the capsule shells decreased after CMC modification. In addition, the nanocapsule cracking ratio of the nanocapsules was 11.0%, which is highly attractive for their application as nano phase change materials.

Topics: Carboxymethylcellulose Sodium; Drug Stability; Formaldehyde; Nanocapsules; Polymerization; Resins, Synthetic; Temperature; Triazines