o-iodoxybenzoic-acid has been researched along with phenyl-ether* in 1 studies
1 other study(ies) available for o-iodoxybenzoic-acid and phenyl-ether
Article | Year |
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Light-Driven Intermolecular Charge Transfer Induced Reactivity of Ethynylbenziodoxol(on)e and Phenols.
Ethynylbenziodoxol(on)es (EBXs) have been widely used in organic synthesis as electrophilic alkyne-transfer reagents involving carbon- and heteroatom-based nucleophiles. However, potential reactions of EBXs with phenols remain uninvestigated. Here, we present the formation of ( Z)-2-iodovinyl phenyl ethers with excellent regio- and stereoselectivity through the reactivity between EBXs and phenols driven by visible light. We propose that this light-activated transformation proceeds through electron donor-acceptor complexes to enable new reactivity beyond existing mechanisms for alkynylation of carbon- and heteroatom-based nucleophiles. This operationally robust process was employed for the synthesis of diverse ( Z)-2-iodovinyl phenyl ethers through irradiating a solution containing a phenyl-EBX, a phenol, and the base Cs Topics: Chemistry Techniques, Synthetic; Halogenation; Iodobenzenes; Light; Models, Molecular; Phenols; Phenyl Ethers; Vinyl Compounds | 2018 |