o-iodoxybenzoic-acid and nitromethane

o-iodoxybenzoic-acid has been researched along with nitromethane* in 1 studies

Other Studies

1 other study(ies) available for o-iodoxybenzoic-acid and nitromethane

Article	Year
Nitromethane with IBX/TBAF as a nitrosating agent: synthesis of nitrosamines from secondary or tertiary amines under mild conditions. The Journal of organic chemistry, 2012, Jan-06, Volume: 77, Issue:1 Aliphatic or aromatic N,N-disubstituted nitrosamine was generated in fair to excellent yield from the reaction of a secondary or tertiary amine with o-iodoxybenzoic acid (IBX) or o-iodosylbenzoic acid (IBA)/R(4)NX (X = halide) and nitromethane. The product yield was strongly influenced by both the halide of R(4)NX and iodanes. IBX gave a higher yield than IBA, while the halides follow F(-) > Cl(-) > Br(-) ∼ I(-). Nitrous acid formed in situ from nitromethane and IBX (or IBA)/halides is likely responsible for the observed reaction. Topics: Amines; Iodobenzenes; Methane; Molecular Structure; Nitroparaffins; Nitrosamines; Nitrosation	2012

Article

Year

Nitromethane with IBX/TBAF as a nitrosating agent: synthesis of nitrosamines from secondary or tertiary amines under mild conditions.

The Journal of organic chemistry, 2012, Jan-06, Volume: 77, Issue:1

Aliphatic or aromatic N,N-disubstituted nitrosamine was generated in fair to excellent yield from the reaction of a secondary or tertiary amine with o-iodoxybenzoic acid (IBX) or o-iodosylbenzoic acid (IBA)/R(4)NX (X = halide) and nitromethane. The product yield was strongly influenced by both the halide of R(4)NX and iodanes. IBX gave a higher yield than IBA, while the halides follow F(-) > Cl(-) > Br(-) ∼ I(-). Nitrous acid formed in situ from nitromethane and IBX (or IBA)/halides is likely responsible for the observed reaction.

Topics: Amines; Iodobenzenes; Methane; Molecular Structure; Nitroparaffins; Nitrosamines; Nitrosation

2012