naphthoquinones and cyclopentanol

naphthoquinones has been researched along with cyclopentanol* in 1 studies

Other Studies

1 other study(ies) available for naphthoquinones and cyclopentanol

Article	Year
Enantioselective Approach to (-)-Hamigeran B and (-)-4-Bromohamigeran B via Catalytic Asymmetric Hydrogenation of Racemic Ketone To Assemble the Chiral Core Framework. Organic letters, 2016, Mar-18, Volume: 18, Issue:6 A new strategy featuring an iridium-catalyzed asymmetric hydrogenation of a racemic ketone via dynamic kinetic resolution to generate a cyclopentanol with three contiguous stereocenters and a SmI2-promoted pinacol coupling to install the six-membered ring with correct stereochemistry has been described for the enantioselective total synthesis of (-)-hamigeran B (19 steps, 10.6% overall yield) and (-)-4-bromohamigeran B (19 steps, 12.3% overall yield). Topics: Biological Products; Catalysis; Cyclopentanes; Hydrogenation; Iridium; Ketones; Kinetics; Molecular Structure; Naphthoquinones; Stereoisomerism	2016

Article

Year

Enantioselective Approach to (-)-Hamigeran B and (-)-4-Bromohamigeran B via Catalytic Asymmetric Hydrogenation of Racemic Ketone To Assemble the Chiral Core Framework.

Organic letters, 2016, Mar-18, Volume: 18, Issue:6

A new strategy featuring an iridium-catalyzed asymmetric hydrogenation of a racemic ketone via dynamic kinetic resolution to generate a cyclopentanol with three contiguous stereocenters and a SmI2-promoted pinacol coupling to install the six-membered ring with correct stereochemistry has been described for the enantioselective total synthesis of (-)-hamigeran B (19 steps, 10.6% overall yield) and (-)-4-bromohamigeran B (19 steps, 12.3% overall yield).

Topics: Biological Products; Catalysis; Cyclopentanes; Hydrogenation; Iridium; Ketones; Kinetics; Molecular Structure; Naphthoquinones; Stereoisomerism

2016