n-fluorobenzenesulfonimide and azidotrimethylsilane

n-fluorobenzenesulfonimide has been researched along with azidotrimethylsilane* in 1 studies

Other Studies

1 other study(ies) available for n-fluorobenzenesulfonimide and azidotrimethylsilane

Article	Year
Copper-catalyzed intermolecular aminoazidation of alkenes. Organic letters, 2014, Mar-21, Volume: 16, Issue:6 Copper-catalyzed intermolecular aminoazidation of alkenes is described. This novel methodology provides an efficient approach to vicinal amino azides which can easily be transformed into other valuable amine derivatives. The commercially available N-fluorobenzenesulfonimide (NFSI) is used as a nitrogen-radical precursor and TMSN3 as the N3 source. Yields are moderate to excellent, and for internal alkenes aminoazidation occurs with excellent diastereoselectivity. Topics: Alkenes; Amines; Azides; Catalysis; Copper; Molecular Structure; Silanes; Stereoisomerism; Sulfonamides	2014

Article

Year

Copper-catalyzed intermolecular aminoazidation of alkenes.

Organic letters, 2014, Mar-21, Volume: 16, Issue:6

Copper-catalyzed intermolecular aminoazidation of alkenes is described. This novel methodology provides an efficient approach to vicinal amino azides which can easily be transformed into other valuable amine derivatives. The commercially available N-fluorobenzenesulfonimide (NFSI) is used as a nitrogen-radical precursor and TMSN3 as the N3 source. Yields are moderate to excellent, and for internal alkenes aminoazidation occurs with excellent diastereoselectivity.

Topics: Alkenes; Amines; Azides; Catalysis; Copper; Molecular Structure; Silanes; Stereoisomerism; Sulfonamides

2014