n-deacetyllappaconitine has been researched along with carbene* in 1 studies
1 other study(ies) available for n-deacetyllappaconitine and carbene
Article | Year |
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A model study toward the total synthesis of N-deacetyllappaconitine.
[reaction: see text] A model study leading to the preparation of the AEF rings of N-deacetyllappaconitine is described. The conjugate addition to the alpha-alkyl cyclohexenone 10 proceeded with high diastereocontrol. The Mannich cyclization of 16 to 4 was accomplished by heating with Rexyn-300 and Na(2)SO(4). Topics: Aconitine; Alkylation; Cyclization; Cyclohexanes; Cyclohexenes; Hydrocarbons; Methane; Models, Chemical; Molecular Structure | 2005 |