mycoepoxydiene has been researched along with furan* in 1 studies
1 other study(ies) available for mycoepoxydiene and furan
Article | Year |
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Total synthesis of (+/-)-mycoepoxydiene, a novel fungal metabolite having an oxygen-bridged cyclooctadiene skeleton.
[reaction: see text] The first total synthesis of (+/-)-mycoepoxydiene has been accomplished. A ring-closing olefin metathesis (RCM) approach was employed for the construction of the oxygen-bridged eight-membered bicyclic skeleton. The RCM product was converted to the target natural product featuring the oxidative rearrangement of a furfuryl alcohol introduced as the side chain and the stereoselective 1,2-reduction of a delta-keto-beta,gamma-unsaturated alpha-lactol intermediate. Topics: Bridged-Ring Compounds; Cyclooctanes; Fungi; Furans; Lactones; Maleic Anhydrides; Pyrones | 2002 |