morphinans has been researched along with tetrabutylammonium* in 1 studies
1 other study(ies) available for morphinans and tetrabutylammonium
Article | Year |
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Synthesis of New Morphinan Opioids by TBADT-Catalyzed Photochemical Functionalization at the Carbon Skeleton.
The synthesis of new morphinan opioids by the addition of photochemically generated carbon-centered radicals to substrates containing an enone in the morphinan C-ring, is described. Using tetrabutylammonium decatungstate (TBADT) as a hydrogen atom transfer photocatalyst, diverse radical donors can be used to prepare a variety of C8-functionalized morphinan opioids. This work demonstrates the late-stage modification of complex, highly functionalized substrates. Topics: Analgesics, Opioid; Carbon; Catalysis; Morphinans; Quaternary Ammonium Compounds | 2022 |