morphinans has been researched along with sodium-hydride* in 1 studies
1 other study(ies) available for morphinans and sodium-hydride
| Article | Year |
|---|---|
Synthesis of a stable iminium salt and propellane derivatives.
The treatment of morphinan 1 with NaH and MsCl provided very stable iminium salt 7 possessing propellane skeleton. One of the synthesized iminium salts 7, isobutyl derivative 7b, was crystallized and its structure was determined by X-ray crystallography. The natural bond orbital analysis suggested that the stability of the iminium should result from the stereoelectronic effect (hyperconjugation) attributed to their own structures. Topics: Analgesics, Opioid; Crystallography, X-Ray; Mesylates; Morphinans; Sodium Compounds | 2008 |