monanchorin has been researched along with furan* in 1 studies
1 other study(ies) available for monanchorin and furan
Article | Year |
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De Novo Asymmetric Synthesis of (+)-Monanchorin.
A de novo asymmetric total synthesis of the guanidine alkaloid natural product (+)-monanchorin has been achieved in nine steps from the commodity chemicals furan and caproic acid. The asymmetry of the route was introduced by a Noyori reduction of an acylfuran. In addition, this route relies upon an Achmatowicz rearrangement, a diastereoselective palladium catalyzed glycosylation, reductive amination, and an acid catalyzed bicyclic guanidine mixed acetal formation. Topics: Alkaloids; Alkylation; Biological Products; Bridged Bicyclo Compounds, Heterocyclic; Catalysis; Furans; Glycosylation; Guanidines; Molecular Structure; Palladium; Stereoisomerism | 2015 |