metaphosphoric-acid has been researched along with phosphine* in 1 studies
1 other study(ies) available for metaphosphoric-acid and phosphine
| Article | Year |
|---|---|
Stereospecific coupling of H-phosphinates and secondary phosphine oxides with amines and alcohols: a general method for the preparation of optically active organophosphorus acid derivatives.
The reaction of H-phosphinates and secondary phosphine oxides with amines and alcohols proceeds highly stereospecifically to give the corresponding coupling products with inversion of configuration at the phosphorus center under the Atherton-Todd reaction conditions. This finding leads to the establishment of a general and efficient method for the synthesis of a variety of optically active organophosphorus acid derivatives from the easily available chiral H-phosphinates and secondary phosphine oxides. Topics: Alcohols; Amines; Methods; Optical Rotation; Organophosphorus Compounds; Oxides; Phosphines; Phosphorous Acids; Stereoisomerism | 2010 |