mesoxalonitrile and benzaldehyde

mesoxalonitrile has been researched along with benzaldehyde* in 1 studies

Other Studies

1 other study(ies) available for mesoxalonitrile and benzaldehyde

Article	Year
Activation of TMSCN by N-heterocyclic carbenes for facile cyanosilylation of carbonyl compounds. The Journal of organic chemistry, 2006, Feb-03, Volume: 71, Issue:3 N-Heterocyclic carbenes were found to be highly effective organocatalysts in activating TMSCN for facile cyanosilylation of carbonyl compounds. Cyano transfer from TMSCN to aldehydes and ketones proceeds at room temperature in the presence of only 0.01-0.5 mol % of N-heterocyclic carbene (1), leading to a range of trimethylsilylated cyanohydrins in very good to excellent yields. These conditions are extremely mild and simple and tolerate various functional groups. Topics: Acetophenones; Benzaldehydes; Catalysis; Cyanides; Cyclization; Hydrocarbons; Methane; Molecular Structure; Nitriles; Trimethylsilyl Compounds	2006

Article

Year

Activation of TMSCN by N-heterocyclic carbenes for facile cyanosilylation of carbonyl compounds.

The Journal of organic chemistry, 2006, Feb-03, Volume: 71, Issue:3

N-Heterocyclic carbenes were found to be highly effective organocatalysts in activating TMSCN for facile cyanosilylation of carbonyl compounds. Cyano transfer from TMSCN to aldehydes and ketones proceeds at room temperature in the presence of only 0.01-0.5 mol % of N-heterocyclic carbene (1), leading to a range of trimethylsilylated cyanohydrins in very good to excellent yields. These conditions are extremely mild and simple and tolerate various functional groups.

Topics: Acetophenones; Benzaldehydes; Catalysis; Cyanides; Cyclization; Hydrocarbons; Methane; Molecular Structure; Nitriles; Trimethylsilyl Compounds

2006