meloscine and cyclopropane

meloscine has been researched along with cyclopropane* in 1 studies

Other Studies

1 other study(ies) available for meloscine and cyclopropane

ArticleYear
A short total synthesis of (±)-epimeloscine and (±)-meloscine enabled by a cascade radical annulation of a divinylcyclopropane.
    Journal of the American Chemical Society, 2011, Jul-13, Volume: 133, Issue:27

    The first stereoselective synthesis of epimeloscine has been accomplished in 13 total steps with a longest linear sequence of 10 steps. The core of the synthesis takes only five steps, the key ones being acylation, stereoselective tandem radical cyclization of a divinylcyclopropane to make two rings, and group-selective ring-closing metathesis of the resulting divinylcyclopentane to make the last ring.

    Topics: Acylation; Cyclization; Cyclopropanes; Polycyclic Compounds; Quinolines; Stereoisomerism; Vinyl Compounds

2011