meloscine has been researched along with cyclopropane* in 1 studies
1 other study(ies) available for meloscine and cyclopropane
Article | Year |
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A short total synthesis of (±)-epimeloscine and (±)-meloscine enabled by a cascade radical annulation of a divinylcyclopropane.
The first stereoselective synthesis of epimeloscine has been accomplished in 13 total steps with a longest linear sequence of 10 steps. The core of the synthesis takes only five steps, the key ones being acylation, stereoselective tandem radical cyclization of a divinylcyclopropane to make two rings, and group-selective ring-closing metathesis of the resulting divinylcyclopentane to make the last ring. Topics: Acylation; Cyclization; Cyclopropanes; Polycyclic Compounds; Quinolines; Stereoisomerism; Vinyl Compounds | 2011 |