marneral has been researched along with galbanic-acid* in 1 studies
1 other study(ies) available for marneral and galbanic-acid
Article | Year |
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Total synthesis and structural confirmation of ent-galbanic acid and marneral.
By capitalizing on a highly selective Claisen rearrangement, ent-galbanic acid 1 and (+)-marneral 2 have been synthesized. The relative configurations of (+)- 1 and (+)- 2 were unambiguously established by X-ray crystallographic analysis of the precursors 11a and 20, with the absolute configuration ensuing from their derivation from R-pulegone. In this way, the controversial issue of the configuration of galbanic acid was unequivocally settled. Topics: Coumarins; Crystallography, X-Ray; Models, Molecular; Molecular Structure; Triterpenes | 2008 |