marinomycin-a and stannane

marinomycin-a has been researched along with stannane* in 1 studies

Other Studies

1 other study(ies) available for marinomycin-a and stannane

Article	Year
An efficient and stereoselective synthesis of the monomeric counterpart of marinomycin A. Organic letters, 2007, Apr-12, Volume: 9, Issue:8 [structure: see text] The monomeric counterpart of marinomycin A, an antitumor-antibiotic marine natural product, was synthesized efficiently in 11 steps from the commercially available ethyl (R)-(-)-3-hydroxybutyrate. The strategy was highlighted by a crucial regio- and stereoselective cross-metathesis to form the C20-C21 double bond, enantioselective allyltitanations to control the configuration of the C17, C23, and C25 stereogenic centers, and a stereocontrolled construction of the tetraene moiety based on an original Horner-Wadsworth-Emmons olefination followed by a Pd-catalyzed cross-coupling. Topics: Alkenes; Iodides; Lactones; Macrolides; Molecular Structure; Stereoisomerism; Tin Compounds	2007

Article

Year

An efficient and stereoselective synthesis of the monomeric counterpart of marinomycin A.

Organic letters, 2007, Apr-12, Volume: 9, Issue:8

[structure: see text] The monomeric counterpart of marinomycin A, an antitumor-antibiotic marine natural product, was synthesized efficiently in 11 steps from the commercially available ethyl (R)-(-)-3-hydroxybutyrate. The strategy was highlighted by a crucial regio- and stereoselective cross-metathesis to form the C20-C21 double bond, enantioselective allyltitanations to control the configuration of the C17, C23, and C25 stereogenic centers, and a stereocontrolled construction of the tetraene moiety based on an original Horner-Wadsworth-Emmons olefination followed by a Pd-catalyzed cross-coupling.

Topics: Alkenes; Iodides; Lactones; Macrolides; Molecular Structure; Stereoisomerism; Tin Compounds

2007