maneb and chlorine-dioxide

maneb has been researched along with chlorine-dioxide* in 2 studies

Other Studies

2 other study(ies) available for maneb and chlorine-dioxide

ArticleYear
Determination of degradation products and pathways of mancozeb and ethylenethiourea (ETU) in solutions due to ozone and chlorine dioxide treatments.
    Journal of agricultural and food chemistry, 2003, Feb-26, Volume: 51, Issue:5

    The objective of the present study was to determine the degradation products of mancozeb and ethylenethiourea (ETU) and elucidate the possible degradation pathways in solution as a result of chemical oxidation using ozone and chlorine dioxide. This study was developed in a solution at 100 ppm of mancozeb and ETU concentration over the course of 60 min. Two different oxidizing agents used in this study were (1) ozone at 3 ppm and (2) chlorine dioxide at 20 ppm. Ozone was continuously provided throughout the course of the reaction. Degradation products were detected with high-resolution GC-MS. The total analysis time was 4 min per sample combined with rapid GC separation and time-of-flight mass spectrometry (TOFMS). Hydrolysis of mancozeb led to m/z 144 ion fragmentation, which is 5-imidazoledithiocarboxylic acid, as a major degradation product. ETU showed M(+) 102, which corresponds to its mass, indicating this compound was stable in distilled water and did not undergo hydrolysis during 60 min. The average retention times of mancozeb and ETU were approximately 181-189 and 210-230 s, respectively. Ozonation of mancozeb produced ETU as a major product. Treatment of ETU with ozone produced several degradation compounds. From prolonged ozonation, the CS(2) or CS group was removed. Overall, several byproducts identified were M(+) 60, M(+) 84, M(+) 163, M(+) 117, and M(+) 267 by ozone and M(+) 117, M(+) 86, and M(+) 163 by chlorine dioxide treatment. Several of these have been reported, but others have never been reported previously.

    Topics: Chlorine Compounds; Ethylenethiourea; Gas Chromatography-Mass Spectrometry; Hydrogen-Ion Concentration; Kinetics; Maneb; Oxides; Ozone; Solutions; Zineb

2003
Chlorine and chlorine dioxide treatment to reduce or remove EBDCs and ETU residues in a solution.
    Journal of agricultural and food chemistry, 2002, Jul-31, Volume: 50, Issue:16

    Calcium hypochlorite (Ca(OCl)(2)) and chlorine dioxide (ClO(2)), common disinfecting and bleaching chemicals used in the food industry, are potent oxidizing agents. In this paper, the degradation effects of chlorine dioxide on mancozeb and ethylenethiourea (ETU) residues were investigated in a model system and compared with those of liquid chlorine, under various conditions such as differing concentration, pH, reaction time, and temperature. All samples were analyzed for residues by GLC and HPLC. Rate of mancozeb degradation was dependent on pH, with pH 4.6 being the most effective. Mancozeb residues decreased 40-100% with chlorine and chlorine dioxide treatments. ETU residue concentrations in mancozeb solutions were monitored over 60 min. Under controlled conditions, the ETU residue concentrations increased up to 15 min reaction time and then decreased in all three pH ranges. Treatment with both chlorine and chlorine dioxide at pH 4.6, yielded no ETU residues at both 10 and 21 degrees C. The results show that chlorine dioxide gives excellent degradation effects at lower concentrations than liquid chlorine.

    Topics: Calcium Compounds; Chlorine; Chlorine Compounds; Chromatography, Gas; Chromatography, High Pressure Liquid; Ethylenethiourea; Food Industry; Fungicides, Industrial; Hydrogen-Ion Concentration; Hydrolysis; Kinetics; Maneb; Oxidation-Reduction; Oxides; Pesticide Residues; Solutions; Water; Zineb

2002