macbecin-i has been researched along with herbimycin* in 1 studies
1 other study(ies) available for macbecin-i and herbimycin
Article | Year |
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Studies on the syntheses of benzoquinone ansamycin antibiotics. Syntheses of the C5-C15 subunits of macbecin I, geldanamycin, and herbimycin A.
[reaction: see text] A general and convergent route to the C(5)-C(15) subunits of the benzoquinone ansamycin antibiotics macbecin I, geldanamycin, and herbimycin A is described. Each subunit is prepared by the stepwise coupling of differentially functionalized aldehydes with a pentenyl dianion equivalent derived from diastereoselective pentynylation and regioselective reductive coupling. Topics: Anti-Bacterial Agents; Benzoquinones; Lactams, Macrocyclic; Molecular Structure; Rifabutin; Stereoisomerism | 2006 |