lithium-cobalt-oxide and cobalt-oxide

The global market for battery electric vehicles (BEVs) is continuously increasing which results in higher material demand for the production of Li-ion batteries (LIBs). Therefore, the end of life (EOL) of batteries must be handled properly through reusing or recycling to minimize the supply chain issues in future LIBs. This study analyses the global distribution of EOL lithium nickel manganese cobalt (NMC) oxide batteries from BEVs. The Stanford estimation model is used, assuming that the lifespan of NMC batteries follows a Weibull distribution. The global sales data of NMC batteries from 2009 to 2018 were collected and the sales data from 2019 to 2030 were estimated based on historical trends and BEV development plans in the top 10 countries for BEV sales. The result shows a view of EOL NMC batteries worldwide. In 2038, China, South Korea and the United States (US) will be the three leading countries in the recovery of NMC battery materials. An overall global flow of NMC battery materials (aluminium, copper, manganese, steel, lithium and graphite/carbon) was also predicted in this research. This study estimated the waste potential of NMC battery materials specifically in the top 10 countries and also in other countries. Finally, the economic value estimation results for recovered materials indicated that copper, aluminium and manganese will have cumulative economic values of 7.9, 4.4 and 3.9 billion US dollars in 2038, respectively. As this study considers the different specific energy of NMC batteries in the coming years due to technological advancement, the findings can provide a more realistic insight into the future demand for NMC battery materials. This study reveals that a high number of EOL NMC batteries will be accumulated in 2038 in several countries. Therefore, large-scale recycling infrastructures should be set up to improve the efficiency of the recovery of battery materials.

Topics: Aluminum; Cobalt; Copper; Electric Power Supplies; Lithium; Manganese; Nickel; Oxides; Recycling

Lithium intercalation compounds such as lithium nickel manganese cobalt oxide (NMC) and lithium cobalt oxide (LCO) are used extensively in lithium batteries. Because there is currently little economic incentive for recycling, chances are greater that batteries will end up in landfills or waste in the environment. In addition, the toxicity of these battery materials traditionally has not been part of the design process. Therefore, to determine the environmental impact and the possibility of alternative battery materials, representative complex battery nanomaterials, LCO and NMC, were synthesized, and toxicity was assessed in Daphnia magna. Toxicity was determined by assessing LCO and NMC at concentrations in the range of 0.1 to 25 mg/L. Acute studies (48 h) showed no effect to daphnid survival at 25 mg/L, whereas chronic studies (21 d) show significant impacts to daphnid reproduction and survival at concentrations of 0.25 mg/L for LCO and 1.0 mg/L for NMC. Dissolved metal exposures showed no effect at the amounts measured in suspension, and supernatant controls could not reproduce the effects of the particles, indicating a nanomaterial-specific impact. Genes explored in the present study were actin, glutathione-s-transferase, catalase, 18s, metallothionein, heat shock protein, and vitellogenin. Down-regulation of genes important in metal detoxification, metabolism, and cell maintenance was observed in a dose-dependent manner. The results show that battery material chemical composition can be altered to minimize environmental impacts. Environ Toxicol Chem 2017;36:2493-2502. © 2017 SETAC.

Topics: Animals; Cobalt; Daphnia; Electric Power Supplies; Manganese; Nanostructures; Oxides