Compounds > lithium-chloride

lithium-chloride and methyllithium

lithium-chloride has been researched along with methyllithium* in 2 studies

Other Studies

2 other study(ies) available for lithium-chloride and methyllithium

ArticleYear
MeLi + LiCl in THF: one heterodimer and no tetramers.
    The Journal of organic chemistry, 2010, Sep-03, Volume: 75, Issue:17

    The structure of the aggregates formed when mixing methyllithium and lithium chloride in THF has been studied by multinuclear magnetic resonance at 170 K. The data suggest that only one new entity is observed, that is the dimer [(MeLi)(LiCl)], in equilibrium (K approximately 0.6) with [MeLi](4) and [LiCl](2). NMR diffusion measurements lead to the conclusion that this dimer is trisolvated in THF at 170 K, a solvation scheme in agreement with DFT computations.

    Topics: Computer Simulation; Dimerization; Furans; Lithium Chloride; Magnetics; Molecular Structure; Organometallic Compounds

2010
Acceleration of the substitution of silanes with Grignard reagents by using either LiCl or YCl3/MeLi.
    Angewandte Chemie (International ed. in English), 2010, Oct-11, Volume: 49, Issue:42

    Topics: Catalysis; Lithium Chloride; Molecular Structure; Organometallic Compounds; Silanes; Yttrium

2010