kaitocephalin has been researched along with serinol* in 1 studies
1 other study(ies) available for kaitocephalin and serinol
Article | Year |
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Total synthesis of (-)-kaitocephalin.
(-)-Kaitocephalin has been synthesized. With the C9 stereocenter from Garner's aldehyde, the C4 quaternary carbon was installed by the desymmetrization of the Cbz-protected serinol. The remaining stereogenic centers were generated through mercuriocyclization, epoxidation and regioselective epoxide opening, in which the quaternary carbon most likely played crucial roles in the stereoinduction. Topics: Aldehydes; Cyclization; Epoxy Compounds; Propanolamines; Propylene Glycols; Pyrroles; Stereoisomerism | 2013 |