iron-tetraphenylporphyrin and hydroxide-ion

iron-tetraphenylporphyrin has been researched along with hydroxide-ion* in 1 studies

Other Studies

1 other study(ies) available for iron-tetraphenylporphyrin and hydroxide-ion

Article	Year
Stabilization of higher-valent states of iron porphyrin by hydroxide and methoxide ligands: electrochemical generation of iron(IV)-oxo porphyrins. Proceedings of the National Academy of Sciences of the United States of America, 1985, Volume: 82, Issue:13 An electrochemical study of hydroxide- and methoxide-ligated iron(III) tetraphenylporphyrins possessing ortho-phenyl substituents that block mu-oxo dimer formation has been carried out. Ligation by these strongly basic oxyanions promotes the formation of iron(IV)-oxo porphyrins upon one-electron oxidation. Further one-electron oxidation of the latter provides the iron(IV)-oxo porphyrin pi-cation radical. These results are discussed in terms of chemical model studies and the enzymatic intermediate compounds I and II of the peroxidases. Topics: Chlorides; Cytochrome P-450 Enzyme System; Electrochemistry; Hydroxides; Iron; Metalloporphyrins; Methanol; Oxidation-Reduction; Peroxidases; Porphyrins	1985

Article

Year

Stabilization of higher-valent states of iron porphyrin by hydroxide and methoxide ligands: electrochemical generation of iron(IV)-oxo porphyrins.

Proceedings of the National Academy of Sciences of the United States of America, 1985, Volume: 82, Issue:13

An electrochemical study of hydroxide- and methoxide-ligated iron(III) tetraphenylporphyrins possessing ortho-phenyl substituents that block mu-oxo dimer formation has been carried out. Ligation by these strongly basic oxyanions promotes the formation of iron(IV)-oxo porphyrins upon one-electron oxidation. Further one-electron oxidation of the latter provides the iron(IV)-oxo porphyrin pi-cation radical. These results are discussed in terms of chemical model studies and the enzymatic intermediate compounds I and II of the peroxidases.

Topics: Chlorides; Cytochrome P-450 Enzyme System; Electrochemistry; Hydroxides; Iron; Metalloporphyrins; Methanol; Oxidation-Reduction; Peroxidases; Porphyrins

1985