iridoids has been researched along with phosphine* in 1 studies
1 other study(ies) available for iridoids and phosphine
Article | Year |
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Asymmetric total synthesis of the iridoid beta-glucoside (+)-geniposide via phosphine organocatalysis.
Phosphine-catalyzed [3 + 2] cycloaddition of ethyl-2,3-butadienoate with enone (S)-3b occurs with high levels of regio- and stereocontrol to deliver the cis-fused cyclopenta[c]pyran 4 characteristic of the iridoid family of natural products. Cycloadduct 4 was converted to the iridoid glycoside (+)-geniposide in 10 steps. Topics: Catalysis; Iridoids; Molecular Structure; Phosphines; Stereoisomerism | 2009 |