iridoids and phosphine

iridoids has been researched along with phosphine* in 1 studies

Other Studies

1 other study(ies) available for iridoids and phosphine

ArticleYear
Asymmetric total synthesis of the iridoid beta-glucoside (+)-geniposide via phosphine organocatalysis.
    Organic letters, 2009, Apr-16, Volume: 11, Issue:8

    Phosphine-catalyzed [3 + 2] cycloaddition of ethyl-2,3-butadienoate with enone (S)-3b occurs with high levels of regio- and stereocontrol to deliver the cis-fused cyclopenta[c]pyran 4 characteristic of the iridoid family of natural products. Cycloadduct 4 was converted to the iridoid glycoside (+)-geniposide in 10 steps.

    Topics: Catalysis; Iridoids; Molecular Structure; Phosphines; Stereoisomerism

2009