iridoids has been researched along with iridolactone* in 2 studies
2 other study(ies) available for iridoids and iridolactone
| Article | Year |
|---|---|
Total syntheses of several iridolactones and the putative structure of noriridoid scholarein A: an intramolecular Pauson-Khand reaction based one-stop synthetic solution.
A simple and general approach towards the total syntheses of several iridolactones such as (±)-boschnialactone, (±)-7-epi-boschnialactone, (±)-teucriumlactone, (±)-iridomyrmecin, (±)-isoboonein, (±)-7-epi-argyol, (±)-scabrol A, (±)-7-epi-scabrol A, and (±)-patriscabrol as well as the putative structure of scholarein A is delineated. The synthetic strategy features a diastereoselective intramolecular Pauson-Khand reaction (IPKR) to construct the iridoid framework followed by some strategic synthetic manipulations to access the targeted monoterpenes including those having diverse oxy-functionalization patterns and with 3-5 contiguous stereogenic centres in a highly stereocontrolled manner. Also, the present endeavour includes the first total synthesis of scabrol A. Topics: Indole Alkaloids; Iridoids; Lactones; Molecular Conformation; Solutions; Stereoisomerism | 2019 |
Enantio- and diastereocontrolled synthesis of (-)-iridolactone and (+)-pedicularis-lactone.
[structure: see text]. Two iridoid lactones, (-)-iridolactone and (+)-pedicularis-lactone, have been synthesized in an enantio- and diastereocontrolled manner starting from a tricyclic chiral building block serving as a synthetic equivalent of chiral 3-(hydroxymethyl)cyclopenta-2,4-dien-1-ol. Topics: Asia; Indicators and Reagents; Iridoids; Lactones; Plants, Medicinal; Stereoisomerism | 2001 |