incrustoporin and diethylzinc

incrustoporin has been researched along with diethylzinc* in 1 studies

Other Studies

1 other study(ies) available for incrustoporin and diethylzinc

Article	Year
Addition of diethylzinc to dicobalt hexacarbonyl complexes of alpha,beta-acetylenic aldehydes with virtually complete enantioselectivity. A formal synthesis of (+)-incrustoporin. Organic letters, 2002, Jul-11, Volume: 4, Issue:14 [reaction: see text] The addition of diethylzinc to dicobalt hexacarbonyl complexes of acetylenes mediated by (R)-2-piperidino-1,1,2-triphenylethanol takes place with very high enantioselectivity (96-99% ee) to afford the S enantiomers of dicobalt hexacarbonyl complexes of 1-alkynyl-1-propanols. The utility of this process is exemplified by the development of a short, highly enantioselective (99% ee) synthesis of unnatural incrustoporin. Topics: 4-Butyrolactone; Acetylene; Aldehydes; Antifungal Agents; Chromatography, High Pressure Liquid; Cobalt; Indicators and Reagents; Ligands; Organometallic Compounds; Solutions; Stereoisomerism	2002

Article

Year

Addition of diethylzinc to dicobalt hexacarbonyl complexes of alpha,beta-acetylenic aldehydes with virtually complete enantioselectivity. A formal synthesis of (+)-incrustoporin.

Organic letters, 2002, Jul-11, Volume: 4, Issue:14

[reaction: see text] The addition of diethylzinc to dicobalt hexacarbonyl complexes of acetylenes mediated by (R)-2-piperidino-1,1,2-triphenylethanol takes place with very high enantioselectivity (96-99% ee) to afford the S enantiomers of dicobalt hexacarbonyl complexes of 1-alkynyl-1-propanols. The utility of this process is exemplified by the development of a short, highly enantioselective (99% ee) synthesis of unnatural incrustoporin.

Topics: 4-Butyrolactone; Acetylene; Aldehydes; Antifungal Agents; Chromatography, High Pressure Liquid; Cobalt; Indicators and Reagents; Ligands; Organometallic Compounds; Solutions; Stereoisomerism

2002