imperanene has been researched along with vanillin* in 1 studies
1 other study(ies) available for imperanene and vanillin
Article | Year |
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Enantioselective synthesis of imperanene via enzymatic asymmetrization of an intermediary 1,3-diol.
[reaction: see text] Using a chemoenzymatic synthetic strategy, (S)-imperanene and its (R)-enantiomer has been synthesized from vanillin in nine steps. The key step in the synthesis involves the use of Pseudomonas cepacia lipase (PS-30) to induce asymmetrization of the intermediary prochiral 1,3-diol in >97% ee. Topics: Benzaldehydes; Burkholderia cepacia; Catalysis; Lipase; Molecular Structure; Phenols; Stereoisomerism | 2004 |