imidazolone has been researched along with isothiocyanic-acid* in 1 studies
1 other study(ies) available for imidazolone and isothiocyanic-acid
| Article | Year |
|---|---|
Transannulation of 1-sulfonyl-1,2,3-triazoles with heterocumulenes.
Readily available 1-mesyl-1,2,3-triazoles are efficiently converted into a variety of imidazolones and thiazoles by Rh(II)-catalyzed denitrogenative reactions with isocyanates and isothiocyanates, respectively. The proposed triazole-diazoimine equilibrium results in the formation of highly reactive azavinyl metal-carbenes, which react with heterocumulenes causing an apparent swap of 1,2,3-triazole core for another heterocycle. Topics: Catalysis; Imidazoles; Isocyanates; Isothiocyanates; Methane; Polyenes; Rhodium; Sulfinic Acids; Thiazoles; Triazoles | 2013 |