hydrogen has been researched along with rhodium in 189 studies
| Timeframe | Studies, this research(%) | All Research% |
|---|---|---|
| pre-1990 | 2 (1.06) | 18.7374 |
| 1990's | 3 (1.59) | 18.2507 |
| 2000's | 61 (32.28) | 29.6817 |
| 2010's | 115 (60.85) | 24.3611 |
| 2020's | 8 (4.23) | 2.80 |
| Authors | Studies |
|---|---|
| Kaplan, S; Moore, MD | 1 |
| Barton, JK; Rehmann, JP | 1 |
| Cuendet, P; Grätzel, M; Hall, DO; Rao, KK | 1 |
| Baker, DC; Mao, J | 1 |
| Adima, A; Moreau, JJ; Wong Chi Man, M | 1 |
| Bargon, J; Brinkmann, A; Lange, S; Leitner, W; Trautner, P; Woelk, K | 1 |
| Iseki, K; Kuroki, Y; Sakamaki, Y | 1 |
| Babu, SA; Dastidar, P; Gunanathan, C; Muthusamy, S; Suresh, E | 1 |
| Huddleston, RR; Jang, HY; Krische, MJ | 1 |
| Brookhart, M; Diaz-Requejo, MM; DiSalvo, D | 1 |
| Campos, KR; Evans, DA; Michael, FE; Tedrow, JS | 1 |
| Hoge, G | 1 |
| HYMAN, AL; HYMAN, ES; QUIROZ, AC | 1 |
| Genet, JP | 1 |
| Gray, TG; Nocera, DG; Veige, AS | 1 |
| Carlton, L | 1 |
| Cook, KS; Fan, Y; Hall, MB; Hartwig, JF; Incarvito, CD; Webster, CE | 1 |
| Gao, W; Liu, D; Wang, C; Zhang, X | 1 |
| Bernsmann, H; Boogers, JA; de Vries, AH; de Vries, JG; Feringa, BL; Hoen, R; Meetsma, A; Minnaard, AJ; Tiemersma-Wegman, TD | 1 |
| Cho, CW; Kong, JR; Krische, MJ | 1 |
| de Vries, JG; Feringa, BL; Minnaard, AJ; Panella, L | 1 |
| Breher, F; Büttner, T; Grützmacher, H; Le Floch, P; Maire, P | 1 |
| Chen, Q; Hao, X; Kuriyama, M; Soeta, T; Tomioka, K; Yamada, K | 1 |
| Brayshaw, SK; Green, JC; Ingleson, MJ; Kociok-Köhn, G; McIndoe, JS; Raithby, PR; Weller, AS | 1 |
| Brayshaw, SK; Green, JC; Kociok-Köhn, G; Sceats, EL; Weller, AS | 1 |
| Bergman, RG; Ellman, JA; Lewis, JC; Wu, JY | 1 |
| Boz, I; Pozan, GS | 1 |
| Bakac, A | 1 |
| Blagg, RJ; Charmant, JP; Connelly, NG; Haddow, MF; Orpen, AG | 1 |
| Hou, GH; Wang, LX; Xie, JH; Zhou, QL | 1 |
| Kozerski, L; Marek, R; Pazderski, L; Sitkowski, J; Szłyk, E; Tousek, J | 1 |
| Jung, CK; Krische, MJ | 1 |
| Fox, JM; Panne, P | 1 |
| Fan, BM; Li, S; Wang, LX; Xie, JH; Zhou, QL | 1 |
| de Vries, JG; Feringa, BL; Hoen, R; Lefort, L; Minnaard, AJ; Procuranti, B; Tiemersma-Wegman, T | 1 |
| de Bruin, B; Hetterscheid, DG; Kicken, RJ; Klop, M; Reijerse, EJ; Smits, JM | 1 |
| Donoghue, PJ; Helquist, P; Wiest, O | 1 |
| Imai, M; Kawahara, N; Nagumo, S; Suemune, H; Tanaka, M | 1 |
| Gavril, D; Georgaka, A; Karaiskakis, G; Loukopoulos, V | 1 |
| Garner, SA; Krische, MJ | 1 |
| Egbebi, A; Spivey, JJ | 1 |
| Halligudi, SB; Joseph, T; Kakade, B; Pillai, V; Shintri, S | 1 |
| Brayshaw, SK; Dallanegra, R; Douglas, TM; Kociok-Köhn, G; Macgregor, SA; Moxham, GL; Vadivelu, P; Weller, AS; Wondimagegn, T | 1 |
| Hartwig, JF; Liu, Z | 1 |
| Chan, KS; de Bruin, B; Dzik, WI; Li, XZ | 1 |
| Gridnev, ID; Hoge, G; Imamoto, T; Kouchi, M; Takahashi, H | 1 |
| Bergman, RG; Ellman, JA; Yotphan, S | 1 |
| Bergman, RG; Berman, AM; Ellman, JA; Lewis, JC | 1 |
| Bojan, V; Hata, H; Kobayashi, Y; Mallouk, TE; Youngblood, WJ | 1 |
| Breit, B; Krossing, I; Laungani, AC; Slattery, JM | 1 |
| Huard, K; Lebel, H | 1 |
| Bergman, RG; Ellman, JA; Lewis, JC | 1 |
| Ding, K; Peng, X; Wang, Z; Xia, C; Zhao, B | 1 |
| Du Bois, J; Olson, DE | 1 |
| Ohki, Y; Sakamoto, M; Tatsumi, K | 1 |
| Castillón, S; Díaz, Y; Marcé, P; Matheu, MI | 1 |
| Fukuzumi, S; Kobayashi, T; Suenobu, T | 2 |
| Chan, SL; Che, CM; Deng, QH; Huang, JS; Thu, HY; Tong, GS | 1 |
| Du Bois, J; Kim, M; Kurokawa, T | 1 |
| Singh, SK; Xu, Q; Zhang, XB | 1 |
| Chen, C; Jung, KW; Nagle, A; Park, CP; Yoon, CH | 1 |
| Atzrodt, J; Brückner, F; Derdau, V; Kroll, C; Zimmermann, J | 1 |
| Misumi, Y; Mizobe, Y; Seino, H | 1 |
| Baik, MH; Brodbelt, JS; Ko, BJ; Kong, JR; Krische, MJ; Mantri, Y; Williams, VM | 1 |
| Bakac, A; Szajna-Fuller, E | 1 |
| Cheng, CH; Parthasarathy, K | 1 |
| Christoforidis, A; Kokkinos, N; Koutsoumba, A; Lazaridou, A; Nikolaou, N; Papadopoulos, CE | 1 |
| Bernskoetter, WH; Brookhart, M; Goldberg, KI; Schauer, CK | 1 |
| Kats, L; Maimon, E; Meyerstein, D | 1 |
| Buchwald, SL; Shen, X | 1 |
| Albrecht, M; Krüger, A; Neels, A | 1 |
| Bianchini, C; Grützmacher, H; Trincado, M; Vizza, F | 1 |
| Chaplin, AB; Green, JC; Harmer, J; Hiney, RM; Weller, AS | 1 |
| Amada, Y; Koso, S; Nakagawa, Y; Tomishige, K | 1 |
| Landis, CR; Watkins, AL | 1 |
| Anada, M; Hashimoto, S; Nambu, H; Oohara, T; Takeda, K | 1 |
| Breit, B; Wieland, J | 1 |
| Bhadbhade, M; Colbran, SB; McSkimming, A | 1 |
| Kudo, A; Miseki, Y | 1 |
| Alagona, G; Ghio, C; Lazzaroni, R | 1 |
| Bergman, RG; Ellman, JA; Tauchert, ME; Tsai, AS | 1 |
| DeAngelis, A; Dmitrenko, O; Fox, JM; Shurtleff, VW | 1 |
| Himeda, Y; Hirose, T; Miyazawa, S | 1 |
| Nelson, CG; Taber, DF | 1 |
| Davies, HM; Morton, D | 1 |
| Li, S; Sarkar, S; Wayland, BB | 1 |
| Arachchige, SM; Brewer, KJ; Shaw, R; Shenoy, V; Tsui, HM; White, TA | 1 |
| Cheng, CH; Muralirajan, K; Parthasarathy, K | 1 |
| Chang, S; Kim, JY; Park, SH | 1 |
| Larock, RC; Shi, F | 1 |
| Bouffard, J; Itami, K | 1 |
| Davies, HM; Dick, AR | 1 |
| Li, WX; Liu, J; Ma, X; Su, HY; Sun, D; Sun, K; Zhao, YH | 1 |
| Bevan, KH; Cui, K; Guo, H; Hakima, AR; Han, X; Kibria, MG; Mi, Z; Paradis, S; Pierre, A; Wang, D | 1 |
| Jiménez, MV; Lahoz, FJ; Lukešová, L; Miranda, JR; Modrego, FJ; Nguyen, DH; Oro, LA; Pérez-Torrente, JJ | 1 |
| Ding, Y; Hutter, J; Iannuzzi, M | 1 |
| Cramer, N; Trans, DN | 1 |
| Chi, KW; Jung, YH; Kim, A; Kim, IS; Kwak, JH; Lee, Y; Park, E; Park, J | 1 |
| Bernarding, J; Bommerich, U; Breitzke, H; Buntkowsky, G; Dillenberger, S; Grünberg, A; Gutmann, T; Ratajczyk, T; Trantzschel, T; Xu, Y | 1 |
| Davies, HM; Hardcastle, KI; Lian, Y | 1 |
| Shen, JJ; Xie, XL; Xu, B; Zhou, QL; Zhu, SF | 1 |
| Hagiwara, H; Hyodo, J; Ida, S; Ishihara, T; Okamoto, Y | 1 |
| Ahuja, R; Ding, Y; Kim, DY; Li, B; Mao, HK; Zou, G | 1 |
| Berry, JF | 1 |
| Panek, JS; Wu, J | 1 |
| Cheng, CH; Jayakumar, J; Parthasarathy, K | 1 |
| Olivo, HF; Ortiz, A; Rodriguez-Cárdenas, E; Romero-Ortega, M; Sabala, R | 1 |
| Cao, B; Chang, M; Huang, K; Li, S; Liu, G; Wu, W; Yu, S; Zhang, X; Zhou, L | 1 |
| Ng, KH; Yu, WY; Zhou, Z | 1 |
| Li, BJ; Shi, ZJ; Wang, HY; Zhu, QL | 1 |
| Cook, TR; Lutterman, DA; McCarthy, BD; Nocera, DG | 1 |
| Davies, HM; Dick, AR; Ghosh, D; Morton, D | 1 |
| DeAngelis, A; Dmitrenko, O; Fox, JM | 1 |
| Lebel, H; Spitz, C; Trudel, C | 1 |
| Liu, Y; Park, CM; Xu, X | 1 |
| Cramer, N; Pham, MV; Ye, B | 1 |
| Aranishi, K; Demirci, UB; Singh, AK; Xu, Q; Zhong, DC | 1 |
| Li, Y; Shi, J; Yang, Y; Zhou, B | 1 |
| Glorius, F; Nimphius, C; Wang, H; Wencel-Delord, J | 1 |
| Hyster, TK; Knörr, L; Rovis, T; Ward, TR | 1 |
| Balas, L; Durand, T; Galano, JM; Oger, C | 1 |
| Chen, D; Fan, X; Li, Y; Zhang, F; Zhang, G; Zhao, Q | 1 |
| Ding, K; Dong, K; Li, Y; Wang, Z | 1 |
| Bakac, A; Carraher, JM | 1 |
| Feng, H; Li, Y; Shi, J; Yang, Y; Zhou, B | 1 |
| Du Bois, J; Roizen, JL; Zalatan, DN | 1 |
| Bouwman, E; Drent, E; Raoufmoghaddam, S | 1 |
| Glorius, F; Shi, Z; Zhao, D | 1 |
| Danoun, G; Gooßen, LJ; Mamone, P | 1 |
| Ikeda, R; Kitagawa, H; Kobayashi, H; Kubota, Y; Kusada, K; Matsumura, S; Nagaoka, K; Sato, K; Sumi, N; Takata, M; Toh, S; Yamamoto, T | 1 |
| Bess, EN; DeLuca, RJ; Du Bois, J; Oderinde, MS; Roizen, JL; Sigman, MS; Tindall, DJ | 1 |
| Nakagawa, Y; Tamura, M; Tomishige, K | 1 |
| Du, X; Lei, M; Tang, Y; Wang, Z; Zhang, X | 1 |
| Castarlenas, R; Di Giuseppe, A; Lahoz, FJ; Oro, LA; Pérez-Torrente, JJ | 1 |
| Barskiy, DA; Chekmenev, EY; Coffey, AM; Koptyug, IV; Kovtunov, KV; Shchepin, RV; Waddell, KW | 1 |
| Shi, J; Wang, X; Xu, HE; Yi, W; Zhao, G | 1 |
| Barskiy, DA; Bukhtiyarov, VI; Chekmenev, EY; Coffey, AM; Inozemtseva, EA; Khudorozhkov, AK; Koptyug, IV; Kovtunov, KV; Prosvirin, IP; Salnikov, OG; Truong, ML; Waddell, KW | 1 |
| Ariga, K; Daimon, Y; Hill, JP; Kanai, M; Kawakami, K; Komatsu, H | 1 |
| Chen, B; Chen, Y; Duan, P; Hong, M; Lan, X; Li, JJ; Lu, L; Lu, Y; Qian, SS; Zhao, J | 1 |
| Gu, LQ; Huang, ZS; Lao, YX; Li, J; Liu, JG; Qiu, ZP; Wang, H; Wu, JQ; Zhang, SS | 1 |
| Davies, HM; Gu, Z; Guptill, DM; Lu, P; Mailyan, A; Wang, H; Zakarian, A | 1 |
| Fernández-Alvarez, FJ; García-Orduña, P; Iglesias, M; Lahoz, FJ; Lázaro, G; Oro, LA; Pérez-Torrente, JJ; Polo, V | 1 |
| Glorius, F; Vásquez-Céspedes, S; Zhao, D | 1 |
| Chepiga, KM; Davies, HM; Itami, K; Yamaguchi, AD; Yamaguchi, J | 1 |
| Dong, L; Huang, JR; Qin, L; Song, Q; Zhu, YQ | 1 |
| Beckwith, RE; Davies, HM; Hamann, LG; He, J | 1 |
| Jia, J; Liu, X; Shi, J; Song, Y; Xu, HE; Yi, W; Zhou, J | 1 |
| Mei, ST; Ouyang, Q; Wang, NJ; Wei, Y | 1 |
| Artigas, MJ; Lahoz, FJ; Luaces, S; Macías, R; Oro, LA | 1 |
| Dauvois, V; Doris, E; Gravel, E; Jawale, DV; Li, H; Namboothiri, IN; Shah, N | 1 |
| Chen, W; Ma, X; Wang, H; Wu, F; Yi, X | 1 |
| Kuninobu, Y; Sueki, S | 1 |
| Ai, W; Li, Y; Tang, H; Wu, Y; Yang, X; Yang, Y; Zhou, B | 1 |
| Li, JH; Ouyang, XH; Pi, R; Song, RJ; Yang, Y; Zhou, MB | 1 |
| Guo, Q; Huang, Q; Lan, J; Li, X; Liu, H; Qin, X; Wang, R; Wu, D; You, J | 1 |
| Coster, MJ; Lombard, FJ | 1 |
| Huang, X; Lan, J; Wang, Y; You, J | 1 |
| Jiao, N; Li, X | 1 |
| Houk, KN; Huckins, JR; Jiménez-Osés, G; Neufeldt, SR; Thiel, OR | 1 |
| Itami, K; Itoh, T; Kanaike, M; Kondo, M; Masaoka, S; Sakamoto, H; Wakabayashi, K | 1 |
| Ai, W; Chen, Z; Li, Y; Tang, H; Wu, Y; Yang, Y; Zhou, B; Zhu, W | 1 |
| Chen, X; Liu, J; Strathmann, TJ; Wang, Y; Werth, CJ | 1 |
| Piou, T; Rovis, T | 1 |
| DeAngelis, A; Fox, JM; Panish, R | 1 |
| Cheng, Y; Li, K; Li, M; Wan, D; Yang, Y; You, J | 1 |
| Barskiy, DA; Chekmenev, EY; Coffey, AM; Manzanera Esteve, IV; Shchepin, RV | 1 |
| Arai, T; Nakagawa, Y; Tamura, M; Tomishige, K | 1 |
| Hartwig, JF; Lee, T | 1 |
| De Feyter, S; Greber, T; Gröning, O; Hemmi, A; Mertens, SF; Muff, S; Osterwalder, J | 1 |
| Chen, YQ; Farmer, ME; Yu, JQ; Zhu, RY | 1 |
| Cokoja, M; Drees, M; Herrmann, WA; Jantke, D; Kühn, FE; Pardatscher, L | 1 |
| Hao, Y; Khan, MU; Li, H; Liu, H; Wang, L; Zeng, J; Zhang, W | 1 |
| Ellman, JA; Halskov, KS; Roth, HS | 1 |
| Cruz, FA; Dong, VM; Shen, Z; Tercenio, QD; Zhu, Y | 1 |
| Blakemore, JD; Day, VW; Henke, WC; Hopkins, JA; Lionetti, D; Moore, WNG | 1 |
| Bacsa, J; Boyarskikh, V; Davies, HML; Liao, K; Musaev, DG; Pickel, TC | 1 |
| Bouchard, LS; Ertas, YN; Glöggler, S; Korchak, S; Liu, Z; Mamone, S; McCormick, J; Verlinsky, L; Wagner, S | 1 |
| Pérez Sestelo, J; Riveiros, R; Sarandeses, LA; Tato, R | 1 |
| Ellman, JA; Hoang, GL; Streit, AD | 1 |
| Miyairi, S; Miyake, M; Saito, H; Shinohara, H; Uchiyama, T | 1 |
| Bai, R; Hou, W; Xiong, H; Xu, H; Zhang, X | 1 |
| Lei, H; Rovis, T | 1 |
| Grimm, AR; Hayashi, T; Kato, S; Onoda, A; Schwaneberg, U; Tachikawa, K | 1 |
| Augustine, SA; Chung, CP; Davison, RT; Dong, VM; Hou, X; Parker, PD | 1 |
| Claverie, J; Tang, C; Tang, W; Wan, F; Wang, N; Zhu, Y | 1 |
| Bacsa, J; Cammarota, RC; Davies, HML; Liu, W; Sigman, MS | 1 |
| Dong, G; Ratchford, BL; Xue, Y; Zhang, R; Zhu, J | 1 |
| Ling, F; Liu, T; Xu, C; Zhang, W; Zhang, Z; Zhong, W | 1 |
11 review(s) available for hydrogen and rhodium
| Article | Year |
|---|---|
Aqueous rhodium(III) hydrides and mononuclear rhodium(II) complexes.
Topics: Deuterium Exchange Measurement; Hydrogen; Kinetics; Ligands; Molecular Structure; Organometallic Compounds; Oxidation-Reduction; Rhodium; Water | 2006 |
Heterogeneous catalytic synthesis of ethanol from biomass-derived syngas.
Topics: Biomass; Carbon Monoxide; Catalysis; Ethanol; Hydrogen; Methanol; Rhodium; Thermodynamics | 2007 |
Direct functionalization of nitrogen heterocycles via Rh-catalyzed C-H bond activation.
Topics: Carbon; Catalysis; Heterocyclic Compounds; Hydrogen; Nitrogen; Rhodium | 2008 |
Guiding principles for site selective and stereoselective intermolecular C-H functionalization by donor/acceptor rhodium carbenes.
Topics: Azo Compounds; Biological Products; Carbon; Catalysis; Hydrogen; Methane; Rhodium; Stereoisomerism | 2011 |
Remote C-H activation via through-space palladium and rhodium migrations.
Topics: Catalysis; Chemistry, Organic; Hydrocarbons, Aromatic; Hydrogen; Palladium; Rhodium; Thermodynamics | 2010 |
Rhodium-catalyzed C-H bond arylation of arenes.
Topics: Catalysis; Chemistry, Organic; Electrons; Hydrocarbons, Aromatic; Hydrogen; Ligands; Oxidative Coupling; Oxygen; Rhodium; Substrate Specificity | 2010 |
Functionalization of carbon-hydrogen bonds through transition metal carbenoid insertion.
Topics: Alkanesulfonates; Catalysis; Chemistry, Organic; Electrons; Hydrocarbons, Aromatic; Hydrogen; Ligands; Organophosphonates; Rhodium; Substrate Specificity | 2010 |
Are alkyne reductions chemo-, regio-, and stereoselective enough to provide pure (Z)-olefins in polyfunctionalized bioactive molecules?
Topics: Alkenes; Alkynes; Boron Compounds; Catalysis; Chemistry Techniques, Synthetic; Hydrogen; Hydrogenation; Oxidation-Reduction; Polyenes; Rhodium; Stereoisomerism; Structure-Activity Relationship; Titanium; Zinc | 2013 |
Selective hydrogenolysis of C-O bonds using the interaction of the catalyst surface and OH groups.
Topics: Biomass; Carbon; Catalysis; Hexoses; Hydrogen; Hydrolysis; Hydroxides; Iridium; Kinetics; Molybdenum; Oxides; Oxygen; Rhenium; Rhodium; Sugar Alcohols | 2014 |
Rhodium(II)-catalysed intramolecular C-H insertion α- to oxygen: reactivity, selectivity and applications to natural product synthesis.
Topics: Biological Products; Carbon; Catalysis; Chemistry Techniques, Synthetic; Hydrogen; Lactones; Oxygen; Rhodium; Stereoisomerism | 2015 |
A Simple and Versatile Amide Directing Group for C-H Functionalizations.
Topics: Amides; Carbon; Catalysis; Chemistry Techniques, Synthetic; Hydrocarbons; Hydrogen; Palladium; Rhodium; Ruthenium | 2016 |
178 other study(ies) available for hydrogen and rhodium
| Article | Year |
|---|---|
Identification of intrinsic high-level resistance to rare-earth oxides and oxyanions in members of the class Proteobacteria: characterization of tellurite, selenite, and rhodium sesquioxide reduction in Rhodobacter sphaeroides.
Topics: Anions; Bacteria; Drug Resistance, Microbial; Hydrogen; Metals, Rare Earth; Mutation; Oxidation-Reduction; Oxidoreductases; Rhodium; Selenium; Subcellular Fractions; Tellurium | 1992 |
1H NMR studies of tris(phenanthroline) metal complexes bound to oligonucleotides: characterization of binding modes.
Topics: Base Sequence; Cobalt; DNA; Hydrogen; Magnetic Resonance Spectroscopy; Molecular Sequence Data; Nucleic Acid Conformation; Oligodeoxyribonucleotides; Organometallic Compounds; Phenanthrolines; Rhodium; Ruthenium; Thermodynamics | 1990 |
Light induced H2 evolution in a hydrogenase-TiO2 particle system by direct electron transfer or via rhodium complexes.
Topics: Clostridium; Desulfovibrio; Edetic Acid; Electron Transport; Hydrogen; Hydrogen-Ion Concentration; Hydrogenase; Light; Methanol; Organometallic Compounds; Oxidation-Reduction; Photochemistry; Pyridines; Rhodium; Titanium | 1986 |
A chiral rhodium complex for rapid asymmetric transfer hydrogenation of imines with high enantioselectivity.
Topics: Hydrogen; Imines; Rhodium; Stereoisomerism | 1999 |
Immobilization of rhodium complexes in chiral organic-inorganic hybrid materials.
Topics: Catalysis; Chemistry; Gels; Hydrogen; Hydrolysis; Ketones; Ligands; Models, Chemical; Rhodium; Spectroscopy, Fourier Transform Infrared; Stereoisomerism; Temperature; Ultraviolet Rays; X-Rays | 2000 |
Mechanistic aspects of dihydrogen activation and transfer during asymmetric hydrogenation in supercritical carbon dioxide.
Topics: Carbon Dioxide; Catalysis; Chemistry; Deuterium; Hydrogen; Ligands; Magnetic Resonance Spectroscopy; Models, Chemical; Pressure; Rhodium; Solvents; Time Factors | 2000 |
Enantioselective rhodium(I)-catalyzed hydrogenation of trifluoromethyl ketones.
Topics: Alcohols; Hydrocarbons, Fluorinated; Hydrogen; Ketones; Rhodium; Stereoisomerism | 2001 |
First example of regiospecific intermolecular C-H insertion reactions of cyclic rhodium carbenoids: novel synthesis of 3-indol-3'-yloxindoles.
Topics: Carbon; Hydrogen; Indoles; Molecular Conformation; Rhodium | 2002 |
Reductive generation of enolates from enones using elemental hydrogen: catalytic C-C bond formation under hydrogenative conditions.
Topics: Alcohols; Aldehydes; Alkenes; Cyclization; Hydrogen; Ketones; Organometallic Compounds; Oxidation-Reduction; Reducing Agents; Rhodium | 2002 |
Synthesis of 1,2-diheteroatom-substituted alkenes via rhodium-catalyzed intramolecular hydrogen transfer.
Topics: Alkenes; Amines; Catalysis; Ethers; Hydrogen; Organometallic Compounds; Rhodium; Silanes | 2003 |
Application of chiral mixed phosphorus/sulfur ligands to enantioselective rhodium-catalyzed dehydroamino acid hydrogenation and ketone hydrosilylation processes.
Topics: Acrylates; Amino Acids; Catalysis; Crystallography, X-Ray; Hydrogen; Hydrogenation; Ketones; Ligands; Models, Molecular; Molecular Conformation; Organometallic Compounds; Organophosphorus Compounds; Palladium; Rhodium; Silanes; Stereoisomerism; Sulfides | 2003 |
Synthesis of both enantiomers of a P-chirogenic 1,2-bisphospholanoethane ligand via convergent routes and application to rhodium-catalyzed asymmetric hydrogenation of CI-1008 (pregabalin).
Topics: Acrylates; Anticonvulsants; Catalysis; Crystallography, X-Ray; Ethane; gamma-Aminobutyric Acid; Hydrogen; Ligands; Molecular Structure; Organophosphorus Compounds; Pregabalin; Pressure; Rhodium; Stereoisomerism | 2003 |
GANTT J: Comparison of the platinum-rhodium-hydrogen electrode, dyedilution, and oxygen methods in detecting shunts.
Topics: Electrodes; Heart Defects, Congenital; Humans; Hydrogen; Oxygen; Platinum; Protons; Rhodium; Tomography, X-Ray Computed | 1960 |
Asymmetric catalytic hydrogenation. Design of new Ru catalysts and chiral ligands: from laboratory to industrial applications.
Topics: Alkenes; Catalysis; Cyclization; Drug Design; Heterocyclic Compounds; Hydrogen; Hydrogenation; Ketones; Kinetics; Ligands; Models, Chemical; Molecular Conformation; Molecular Structure; Organometallic Compounds; Phosphines; Rhodium; Ruthenium; Stereoisomerism | 2003 |
Cooperative bimetallic reactivity: hydrogen activation in two-electron mixed-valence compounds.
Topics: Crystallography, X-Ray; Hydrogen; Iridium; Models, Molecular; Organometallic Compounds; Rhodium; Thermodynamics | 2004 |
Rhodium-103 NMR of [Rh(X)(PPh3)3] [X = Cl, N3, NCO, NCS, N(CN)2, NCBPh3, CNBPh3, CN] and derivatives containing CO, isocyanide, pyridine, H2 and O2. Ligand, solvent and temperature effects.
Topics: Carbon Monoxide; Chlorine Compounds; Hydrogen; Isocyanates; Ligands; Magnetic Resonance Spectroscopy; Models, Molecular; Molecular Conformation; Oxygen; Pyridines; Rhodium; Solvents | 2004 |
Rhodium silyl boryl hydride complexes: comparison of bonding and the rates of elimination of borane, silane, and dihydrogen.
Topics: Boranes; Crystallography, X-Ray; Hydrogen; Models, Molecular; Molecular Conformation; Organometallic Compounds; Rhodium; Silanes | 2004 |
Practical synthesis of enantiopure gamma-amino alcohols by rhodium-catalyzed asymmetric hydrogenation of beta-secondary-amino ketones.
Topics: Amino Alcohols; Catalysis; Hydrogen; Ketones; Magnetic Resonance Spectroscopy; Rhodium; Stereoisomerism | 2005 |
Achiral ligands dramatically enhance rate and enantioselectivity in the Rh/phosphoramidite-catalyzed hydrogenation of alpha,beta-disubstituted unsaturated acids.
Topics: Acids; Acrylates; Catalysis; Hydrogen; Ligands; Methacrylates; Molecular Structure; Organophosphorus Compounds; Phenylpropionates; Rhodium; Stereoisomerism | 2005 |
Hydrogen-mediated reductive coupling of conjugated alkynes with ethyl (N-Sulfinyl)iminoacetates: synthesis of unnatural alpha-amino acids via rhodium-catalyzed C-C bond forming hydrogenation.
Topics: Acetates; Alkynes; Amino Acids; Carbon; Catalysis; Hydrogen; Hydrogenation; Imines; Rhodium | 2005 |
Enantioselective RH-catalyzed hydrogenation of enol acetates and enol carbamates with monodentate phosphoramidites.
Topics: Acetates; Carbamates; Catalysis; Hydrogen; Molecular Structure; Naphthalenes; Organophosphorus Compounds; Rhodium; Stereoisomerism; Substrate Specificity | 2005 |
Heterolytic splitting of hydrogen with rhodium(I) amides.
Topics: Amides; Crystallography, X-Ray; Hydrogen; Models, Chemical; Models, Molecular; Molecular Conformation; Organometallic Compounds; Rhodium; Stereoisomerism | 2005 |
Asymmetric synthesis of 5-arylcyclohexenones by rhodium(I)-catalyzed conjugate arylation of racemic 5-(trimethylsilyl)cyclohexenone with arylboronic acids.
Topics: Boronic Acids; Catalysis; Cyclohexanones; Hydrogen; Isomerism; Ligands; Methylation; Molecular Structure; Phosphines; Rhodium | 2005 |
Holding onto lots of hydrogen: a 12-hydride rhodium cluster that reversibly adds two molecules of H2.
Topics: Crystallography, X-Ray; Hydrogen; Models, Molecular; Organometallic Compounds; Rhodium | 2005 |
A rhodium complex with one Rh...C-C and one Rh...H-C agostic bond.
Topics: Carbon; Crystallography, X-Ray; Hydrogen; Models, Molecular; Molecular Conformation; Organometallic Compounds; Rhodium | 2006 |
Microwave-promoted rhodium-catalyzed arylation of heterocycles through C--H bond activation.
Topics: Azoles; Carbon; Catalysis; Heterocyclic Compounds; Hydrogen; Microwaves; Models, Molecular; Molecular Structure; Rhodium | 2006 |
Catalytic hydrodechlorination of 2,4-dichlorophenol on Pd/Rh/C catalysts.
Topics: Algorithms; Carbon; Catalysis; Chlorine; Chlorophenols; Hydrogen; Kinetics; Models, Chemical; Palladium; Rhodium | 2006 |
Redox activation of a B-H bond: a new route to metallaboratrane complexes.
Topics: Boranes; Boron; Crystallography, X-Ray; Hydrogen; Ligands; Models, Molecular; Molecular Structure; Organometallic Compounds; Oxidation-Reduction; Rhodium | 2006 |
Highly efficient Rh(I)-catalyzed asymmetric hydrogenation of enamines using monodente spiro phosphonite ligands.
Topics: Alkenes; Amines; Biphenyl Compounds; Catalysis; Hydrogen; Ligands; Organophosphonates; Oxidation-Reduction; Pyrrolidines; Rhodium; Spiro Compounds; Stereoisomerism | 2006 |
1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenanthroline.
Topics: 2,2'-Dipyridyl; Carbon Isotopes; Cobalt; Gold; Hydrogen; Magnetic Resonance Spectroscopy; Nitrogen Isotopes; Organogold Compounds; Phenanthrolines; Rhodium | 2007 |
Asymmetric induction in hydrogen-mediated reductive aldol additions to alpha-amino aldehydes catalyzed by rhodium: selective formation of syn-stereotriads directed by intramolecular hydrogen-bonding.
Topics: Alcohols; Aldehydes; Catalysis; Chromatography, High Pressure Liquid; Hydrogen; Hydrogen Bonding; Hydrogenation; Ketones; Molecular Structure; Organometallic Compounds; Oxidation-Reduction; Rhodium; Sensitivity and Specificity; Stereoisomerism; X-Ray Diffraction | 2006 |
Rh-catalyzed intermolecular reactions of alkynes with alpha-diazoesters that possess beta-hydrogens: ligand-based control over divergent pathways.
Topics: Alkynes; Azo Compounds; Catalysis; Cyclopropanes; Hydrogen; Ligands; Organometallic Compounds; Rhodium | 2007 |
Highly enantioselective hydrosilylation/cyclization of 1,6-enynes catalyzed by rhodium(I) complexes of spiro diphosphines.
Topics: Cyclization; Hydrogen; Models, Molecular; Molecular Structure; Phosphines; Rhodium; Silanes; Stereoisomerism | 2007 |
Enantioselective synthesis of beta2-amino acids using rhodium-catalyzed hydrogenation.
Topics: Alcohols; Amino Acids; Catalysis; Chemistry, Organic; Hydrogen; Ligands; Magnetic Resonance Spectroscopy; Models, Chemical; Peptides; Rhodium; Stereoisomerism; Temperature | 2007 |
Hydrogen-atom transfer in open-shell organometallic chemistry: the reactivity of Rh(II)(cod) and Ir(II)(cod) radicals.
Topics: Allyl Compounds; Amides; Amines; Hydrogen; Iridium; Ligands; Mathematics; Molecular Structure; Nitrogen; Organometallic Compounds; Oxidation-Reduction; Rhodium; Spectrum Analysis; X-Ray Diffraction | 2007 |
Ligand and substrate effects on the mechanism of rhodium-catalyzed hydrogenation of enamides.
Topics: Acrylonitrile; Alkenes; Amides; Carbon; Catalysis; Formamides; Hydrogen; Hydrogenation; Indicators and Reagents; Ligands; Molecular Conformation; Phosphines; Rhodium; Stereoisomerism | 2007 |
Nitrile-promoted Rh-catalyzed intermolecular hydroacylation of olefins with salicylaldehyde.
Topics: Acylation; Aldehydes; Alkenes; Catalysis; Hydrogen; Molecular Structure; Nitriles; Rhodium | 2007 |
Inverse gas chromatographic investigation of the active sites related to CO adsorption over Rh/SiO2 catalysts in excess of hydrogen.
Topics: Adsorption; Binding Sites; Carbon Monoxide; Catalysis; Chromatography, Gas; Hydrogen; Rhodium; Silicon Dioxide; Surface Properties | 2007 |
Rhodium-catalyzed reductive mannich coupling of vinyl ketones to N-sulfonylimines mediated by hydrogen.
Topics: Catalysis; Hydrogen; Imines; Ketones; Magnetic Resonance Spectroscopy; Mass Spectrometry; Oxidation-Reduction; Rhodium; Spectroscopy, Fourier Transform Infrared; Sulfones | 2007 |
Nanometer sized tridecylamine capped Rhodium dispersed on high surface area support: catalytic investigations.
Topics: Acyclic Monoterpenes; Adsorption; Catalysis; Hydrogen; Metal Nanoparticles; Microscopy, Electron, Transmission; Models, Chemical; Monoterpenes; Nanotechnology; Nitrogen; Octanols; Pressure; Rhodium; Temperature; Terpenes; X-Ray Diffraction | 2007 |
Intramolecular alkyl phosphine dehydrogenation in cationic rhodium complexes of tris(cyclopentylphosphine).
Topics: Cations; Crystallography, X-Ray; Cyclopentanes; Hydrogen; Hydrogenation; Ligands; Models, Chemical; Models, Molecular; Molecular Structure; Organometallic Compounds; Phosphines; Rhodium; Stereoisomerism; Time Factors | 2008 |
Mild, rhodium-catalyzed intramolecular hydroamination of unactivated terminal and internal alkenes with primary and secondary amines.
Topics: Alkenes; Amination; Amines; Catalysis; Hydrogen; Ligands; Molecular Structure; Rhodium | 2008 |
Carbon-carbon bond activation of 2,2,6,6-tetramethyl-piperidine-1-oxyl by a Rh(II) metalloradical: a combined experimental and theoretical study.
Topics: Binding Sites; Carbon; Cyclic N-Oxides; Free Radicals; Hydrogen; Kinetics; Metalloporphyrins; Models, Chemical; Molecular Structure; Rhodium | 2008 |
Asymmetric hydrogenation catalyzed by a rhodium complex of (R)-(tert-butylmethylphosphino)(di-tert-butylphosphino)methane: scope of enantioselectivity and mechanistic study.
Topics: Amides; Catalysis; Computer Simulation; Esters; Hydrogen; Hydrogenation; Kinetics; Magnetic Resonance Spectroscopy; Models, Chemical; Molecular Conformation; Organometallic Compounds; Reference Standards; Rhodium; Stereoisomerism; Temperature; Thermodynamics | 2008 |
The stereoselective formation of bicyclic enamines with bridgehead unsaturation via tandem C-H bond activation/alkenylation/electrocyclization.
Topics: Alkylation; Alkynes; Amines; Bridged Bicyclo Compounds, Heterocyclic; Carbon; Catalysis; Crystallography, X-Ray; Cyclization; Hydrogen; Imines; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism | 2008 |
Rh(I)-catalyzed arylation of heterocycles via C-H bond activation: expanded scope through mechanistic insight.
Topics: Azoles; Carbon; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Hydrocarbons, Brominated; Hydrogen; Ligands; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism; Time Factors | 2008 |
Direct deposition of trivalent rhodium hydroxide nanoparticles onto a semiconducting layered calcium niobate for photocatalytic hydrogen evolution.
Topics: Calcium; Catalysis; Hydrogen; Hydroxides; Metal Nanoparticles; Microscopy, Electron, Transmission; Niobium; Oxides; Photochemistry; Rhodium; Semiconductors; X-Ray Diffraction | 2008 |
Supramolecular bidentate ligands by metal-directed in situ formation of antiparallel beta-sheet structures and application in asymmetric catalysis.
Topics: Carbon Monoxide; Catalysis; Combinatorial Chemistry Techniques; Crystallography, X-Ray; Hydrogen; Hydrogen Bonding; Ligands; Macromolecular Substances; Models, Chemical; Models, Molecular; Molecular Conformation; Organometallic Compounds; Peptides; Protein Structure, Secondary; Rhodium; Transition Elements | 2008 |
N-tosyloxycarbamates as reagents in rhodium-catalyzed C-H amination reactions.
Topics: Alkanes; Amination; Carbamates; Carbon; Catalysis; Hydrogen; Molecular Structure; Oxazolone; Rhodium | 2008 |
Modular chiral bidentate phosphonites: design, synthesis, and application in catalytic asymmetric hydroformylation reactions.
Topics: Alkenes; Bidens; Catalysis; Crystallography, X-Ray; Formates; Hydrogen; Ligands; Models, Molecular; Molecular Structure; Phosphines; Rhodium; Stereoisomerism | 2008 |
Catalytic C-H amination for the preparation of substituted 1,2-diamines.
Topics: Amination; Carbon; Catalysis; Diamines; Esters; Hydrogen; Hydroxylamine; Models, Chemical; Nitrogen; Oxidation-Reduction; Rhodium; Stereoisomerism; Sulfonamides | 2008 |
Reversible heterolysis of H2 mediated by an M-S(thiolate) bond (M = Ir, Rh): a mechanistic implication for [NiFe] hydrogenase.
Topics: Binding Sites; Deuterium; Hydrogen; Hydrogenase; Iridium; Rhodium; Sulfhydryl Compounds | 2008 |
Synthesis of D- and L-carbocyclic nucleosides via rhodium-catalyzed asymmetric hydroacylation as the key step.
Topics: Acylation; Alcohols; Carboxylic Acids; Catalysis; Hydrogen; Kinetics; Molecular Structure; Nucleosides; Rhodium; Stereoisomerism | 2008 |
Efficient catalytic decomposition of formic acid for the selective generation of H2 and H/D exchange with a water-soluble rhodium complex in aqueous solution.
Topics: Catalysis; Deuterium; Formates; Hydrogen; Models, Molecular; Molecular Structure; Organometallic Compounds; Rhodium; Solubility; Water | 2008 |
Highly selective metal catalysts for intermolecular carbenoid insertion into primary C-H bonds and enantioselective C-C bond formation.
Topics: Alkanes; Carbon; Catalysis; Crystallography, X-Ray; Hydrogen; Porphyrins; Rhodium; Stereoisomerism | 2008 |
Synthesis of 1,3-diamines through rhodium-catalyzed C-H insertion.
Topics: Carbon; Catalysis; Diamines; Hydrogen; Rhodium; Stereoisomerism | 2009 |
Room-temperature hydrogen generation from hydrous hydrazine for chemical hydrogen storage.
Topics: Catalysis; Hydrazines; Hydrogen; Metal Nanoparticles; Nitrogen; Particle Size; Rhodium; Surface Properties; Temperature | 2009 |
Formal aromatic C-H insertion for stereoselective isoquinolinone synthesis and studies on mechanistic insights into the C-C bond formation.
Topics: Carbon; Catalysis; Diazonium Compounds; Hydrogen; Isoquinolines; Kinetics; Models, Molecular; Molecular Conformation; Rhodium; Stereoisomerism; Substrate Specificity | 2009 |
Hydrogen-deuterium exchange reactions of aromatic compounds and heterocycles by NaBD4-activated rhodium, platinum and palladium catalysts.
Topics: Catalysis; Deuterium; Heterocyclic Compounds; Hydrocarbons, Aromatic; Hydrogen; Microwaves; Molecular Structure; ortho-Aminobenzoates; Palladium; Platinum; Rhodium; Tandem Mass Spectrometry; Thermodynamics | 2009 |
Heterolytic cleavage of hydrogen molecule by rhodium thiolate complexes that catalyze chemoselective hydrogenation of imines under ambient conditions.
Topics: Catalysis; Hydrogen; Hydrogenation; Imines; Organometallic Compounds; Pressure; Rhodium; Substrate Specificity; Temperature | 2009 |
ESI-MS, DFT, and synthetic studies on the H(2)-mediated coupling of acetylene: insertion of C=X bonds into rhodacyclopentadienes and Brønsted acid cocatalyzed hydrogenolysis of organorhodium intermediates.
Topics: Acetylene; Alkadienes; Catalysis; Hydrogen; Organometallic Compounds; Rhodium; Spectrometry, Mass, Electrospray Ionization | 2009 |
Base-catalyzed insertion of dioxygen into rhodium-hydrogen bonds: kinetics and mechanism.
Topics: Ammonia; Catalysis; Hydrogen; Hydrogen Bonding; Hydrogen-Ion Concentration; Kinetics; Organometallic Compounds; Oxidation-Reduction; Oxygen; Rhodium; Thermodynamics | 2010 |
Easy access to isoquinolines and tetrahydroquinolines from ketoximes and alkynes via rhodium-catalyzed C-H bond activation.
Topics: Alkynes; Carbon; Catalysis; Cyclization; Hydrogen; Hydroxyquinolines; Isoquinolines; Magnetic Resonance Spectroscopy; Oxidation-Reduction; Oximes; Rhodium; Stereoisomerism | 2009 |
Optimization of cotton seed biodiesel quality (critical properties) through modification of its FAME composition by highly selective homogeneous hydrogenation.
Topics: Biofuels; Biotechnology; Catalysis; Equipment Design; Esterification; Fatty Acids; Gossypium; Hydrogen; Iodine; Methanol; Models, Chemical; Oxygen; Rhodium; Temperature | 2010 |
Characterization of a rhodium(I) sigma-methane complex in solution.
Topics: Chemical Phenomena; Cold Temperature; Half-Life; Hydrogen; Ligands; Magnetic Resonance Spectroscopy; Methane; Molecular Structure; Rhodium; Thermodynamics | 2009 |
Substantial inverse isotope effects in the hydrogen atom abstraction from [(L)ClRh(III)--H/D](+) macrocyclic complexes by methyl radicals in aqueous solutions.
Topics: Hydrogen; Isotopes; Kinetics; Methane; Molecular Structure; Oxidation-Reduction; Rhodium; Water | 2010 |
Rhodium-catalyzed asymmetric intramolecular hydroamination of unactivated alkenes.
Topics: Alkenes; Amination; Catalysis; Hydrogen; Ligands; Molecular Structure; Rhodium; Stereoisomerism | 2010 |
Rhodium-mediated activation of an alkane-type C-H bond.
Topics: Alkanes; Carbon; Catalysis; Crystallography, X-Ray; Heterocyclic Compounds; Hydrogen; Methane; Molecular Conformation; Rhodium | 2010 |
Domino rhodium/palladium-catalyzed dehydrogenation reactions of alcohols to acids by hydrogen transfer to inactivated alkenes.
Topics: Acids; Alcohols; Alkenes; Catalysis; Hydrogen; Ketones; Nanoparticles; Palladium; Rhodium; Silicon Dioxide | 2010 |
Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: [Rh(6)(PCy(3))(6)H(12)](+) and [Rh(6)(PCy(3))(6)H(14)](+).
Topics: Computer Simulation; Electron Spin Resonance Spectroscopy; Hydrogen; Magnetics; Molecular Conformation; Organometallic Compounds; Rhodium; Stereoisomerism | 2010 |
Hydrogenolysis of 1,2-propanediol for the production of biopropanols from glycerol.
Topics: Catalysis; Glycerol; Hydrogen; Propanols; Propylene Glycol; Rhodium | 2010 |
Origin of pressure effects on regioselectivity and enantioselectivity in the rhodium-catalyzed hydroformylation of styrene with (S,S,S)-BisDiazaphos.
Topics: Carbon Monoxide; Catalysis; Hydrogen; Pressure; Rhodium; Stereoisomerism; Styrene | 2010 |
A polymer-supported chiral dirhodium(II) complex: highly durable and recyclable catalyst for asymmetric intramolecular C-H insertion reactions.
Topics: Carbon; Catalysis; Coordination Complexes; Hydrogen; Polymers; Polystyrenes; Rhodium; Stereoisomerism | 2010 |
A combinatorial approach to the identification of self-assembled ligands for rhodium-catalysed asymmetric hydrogenation.
Topics: Catalysis; Combinatorial Chemistry Techniques; Hydrogen; Rhodium | 2010 |
Hydride ion-carrier ability in Rh(I) complexes of a nicotinamide-functionalised N-heterocyclic carbene ligand.
Topics: Crystallography, X-Ray; Electrochemistry; Heterocyclic Compounds; Hydrogen; Ions; Ligands; Methane; Niacinamide; Organometallic Compounds; Rhodium; Spectrometry, Mass, Electrospray Ionization; Spectrophotometry, Ultraviolet | 2010 |
Water splitting over new niobate photocatalysts with tungsten-bronze-type structure and effect of transition metal-doping.
Topics: Alloys; Barium; Catalysis; Hydrogen; Lanthanoid Series Elements; Light; Nickel; Niobium; Oxides; Oxygen; Photochemistry; Potassium; Rhodium; Spectrophotometry; Strontium; Transition Elements; Tungsten; Water | 2011 |
Computational prediction of selectivities in nonreversible and reversible hydroformylation reactions catalyzed by unmodified rhodium-carbonyls.
Topics: Aldehydes; Algorithms; Alkenes; Carbon Monoxide; Catalysis; Computer Simulation; Hydrogen; Models, Chemical; Molecular Conformation; Organometallic Compounds; Oxidation-Reduction; Quantum Theory; Rhodium; Stereoisomerism; Thermodynamics | 2011 |
Rhodium(III)-catalyzed arylation of Boc-imines via C-H bond functionalization.
Topics: Carbon; Catalysis; Formic Acid Esters; Hydrogen; Imines; Pyridines; Rhodium | 2011 |
Photocatalytic production of hydrogen by disproportionation of one-electron-reduced rhodium and iridium-ruthenium complexes in water.
Topics: Catalysis; Coordination Complexes; Electron Transport; Hydrogen; Iridium; Organometallic Compounds; Quantum Theory; Rhodium; Water | 2011 |
Rhodium(II)-catalyzed enantioselective C-H functionalization of indoles.
Topics: Carbon; Catalysis; Hydrogen; Indoles; Models, Molecular; Molecular Conformation; Rhodium; Stereoisomerism; Substrate Specificity | 2011 |
Interconversion between formic acid and H(2)/CO(2) using rhodium and ruthenium catalysts for CO(2) fixation and H(2) storage.
Topics: Bicarbonates; Carbon Dioxide; Catalysis; Electrons; Formates; Hydrogen; Hydrogen-Ion Concentration; Hydrogenation; Rhodium; Ruthenium | 2011 |
Aliphatic C-H to C-C conversion: synthesis of (-)-cameroonan-7α-ol.
Topics: Carbon; Catalysis; Cyclization; Hydrogen; Manganese; Oxidation-Reduction; Rhodium; Sesquiterpenes; Stereoisomerism | 2011 |
Hydrogen and methanol exchange processes for (TMP)Rh-OCH3(CH3OH) in binary solutions of methanol and benzene.
Topics: Benzene; Hydrogen; Methanol; Molecular Structure; Organometallic Compounds; Porphyrins; Rhodium; Solutions | 2011 |
High turnover in a photocatalytic system for water reduction to produce hydrogen using a Ru, Rh, Ru photoinitiated electron collector.
Topics: Aniline Compounds; Catalysis; Electrons; Hydrogen; Organometallic Compounds; Oxidation-Reduction; Photochemical Processes; Rhodium; Ruthenium; Solvents; Water | 2011 |
Regioselective synthesis of indenols by rhodium-catalyzed C-H activation and carbocyclization of aryl ketones and alkynes.
Topics: Alkynes; Carbon; Catalysis; Cyclization; Hydrogen; Indenes; Ketones; Rhodium; Stereoisomerism | 2011 |
Rhodium-catalyzed selective olefination of arene esters via C-H bond activation.
Topics: Alkenes; Benzaldehydes; Benzoates; Carbon; Catalysis; Esters; Hydrogen; Molecular Structure; Oxidation-Reduction; Rhodium | 2011 |
Carbon chain growth by formyl insertion on rhodium and cobalt catalysts in syngas conversion.
Topics: Carbon Monoxide; Catalysis; Cobalt; Formates; Hydrocarbons; Hydrogen; Models, Chemical; Rhodium; Structure-Activity Relationship; Thermodynamics | 2011 |
Wafer-level photocatalytic water splitting on GaN nanowire arrays grown by molecular beam epitaxy.
Topics: Catalysis; Chromium Compounds; Diffusion; Gallium; Hydrogen; Nanowires; Oxygen; Particle Size; Photochemistry; Rhodium; Surface Properties; Water | 2011 |
Hydride mobility in trinuclear sulfido clusters with the core [Rh3(μ-H)(μ3-S)2]: molecular models for hydrogen migration on metal sulfide hydrotreating catalysts.
Topics: Alkadienes; Catalysis; Crystallography, X-Ray; Hydrogen; Models, Molecular; Norbornanes; Rhodium; Sulfides | 2011 |
Investigation of h-BN/Rh(111) nanomesh interacting with water and atomic hydrogen.
Topics: Boron Compounds; Hydrogen; Models, Molecular; Nanostructures; Rhodium; Water | 2011 |
Highly selective rhodium catalyzed domino C-H activation/cyclizations.
Topics: Alkadienes; Carbon; Catalysis; Cyclization; Hydrogen; Indans; Rhodium; Stereoisomerism | 2011 |
Rhodium-catalyzed oxidative ortho-acylation of benzamides with aldehydes: direct functionalization of the sp2 C-H bond.
Topics: Acylation; Aldehydes; Benzamides; Carbon; Catalysis; Hydrogen; Molecular Structure; Oxidation-Reduction; Rhodium | 2011 |
New investigations of technical rhodium and iridium catalysts in homogeneous phase employing para-hydrogen induced polarization.
Topics: Benzene Derivatives; Catalysis; Hydrogen; Iridium; Magnetic Resonance Spectroscopy; Rhodium; Solvents; Styrene; Temperature | 2011 |
Computationally guided stereocontrol of the combined C-H functionalization/Cope rearrangement.
Topics: Acetamides; Azides; Carbon; Chemistry Techniques, Synthetic; Hydrogen; Rhodium; Stereoisomerism | 2011 |
Asymmetric N-H insertion reaction cooperatively catalyzed by rhodium and chiral spiro phosphoric acids.
Topics: Amines; Amino Acids; Catalysis; Hydrogen; Methane; Molecular Structure; Organometallic Compounds; Phosphoric Acids; Rhodium; Spiro Compounds; Stereoisomerism | 2011 |
Synthesis and photocatalytic activity of rhodium-doped calcium niobate nanosheets for hydrogen production from a water/methanol system without cocatalyst loading.
Topics: Catalysis; Hydrogen; Methanol; Nanoshells; Niobium; Organometallic Compounds; Particle Size; Photochemical Processes; Rhodium; Surface Properties; Water | 2011 |
Rhodium dihydride (RhH2) with high volumetric hydrogen density.
Topics: Chemistry; Crystallography, X-Ray; Electrochemistry; Electronics; Hydrogen; Kinetics; Physics; Pressure; Rhodium; Sodium Chloride; Software; Temperature | 2011 |
The role of three-center/four-electron bonds in superelectrophilic dirhodium carbene and nitrene catalytic intermediates.
Topics: Catalysis; Electrons; Hydrogen; Imines; Methane; Models, Theoretical; Molecular Structure; Rhodium | 2012 |
Total synthesis of (-)-virginiamycin M2: application of crotylsilanes accessed by enantioselective Rh(II) or Cu(I) promoted carbenoid Si-H insertion.
Topics: Alkenes; Alkynes; Anti-Bacterial Agents; Catalysis; Chromatography, High Pressure Liquid; Copper; Cyclization; Humans; Hydrogen; Magnetic Resonance Spectroscopy; Molecular Structure; Oxidation-Reduction; Rhodium; Silanes; Silicon; Stereoisomerism; Virginiamycin | 2011 |
One-pot synthesis of isoquinolinium salts by rhodium-catalyzed C-H bond activation: application to the total synthesis of oxychelerythrine.
Topics: Alkynes; Amines; Benzaldehydes; Benzophenanthridines; Carbon; Catalysis; Cyclization; Hydrogen; Isoquinolines; Rhodium; Salts | 2012 |
Chemoselective aromatic C-H insertion of α-diazo-β-ketoesters catalyzed by dirhodium(II) carboxylates.
Topics: Azo Compounds; Carbon; Carboxylic Acids; Catalysis; Esters; Hydrogen; Molecular Structure; Rhodium | 2012 |
Highly regioselective isomerization-hydroaminomethylation of internal olefins catalyzed by Rh complex with Tetrabi-type phosphorus ligands.
Topics: Alkenes; Amination; Catalysis; Hydrogen; Ligands; Methylation; Molecular Structure; Phosphorus; Rhodium; Stereoisomerism | 2012 |
Rhodium(III)-catalyzed intermolecular direct amination of aromatic C-H bonds with N-chloroamines.
Topics: Amination; Carbon; Catalysis; Chloramines; Hydrogen; Molecular Structure; Rhodium | 2012 |
Rhodium/copper-catalyzed annulation of benzimides with internal alkynes: indenone synthesis through sequential C-H and C-N cleavage.
Topics: Alkynes; Carbon; Catalysis; Copper; Cyclization; Hydrogen; Imides; Nitrogen; Rhodium | 2012 |
Halogen oxidation and halogen photoelimination chemistry of a platinum-rhodium heterobimetallic core.
Topics: Hydrogen; Organometallic Compounds; Oxidation-Reduction; Photochemical Processes; Platinum; Quantum Theory; Rhodium | 2012 |
Convenient method for the functionalization of the 4- and 6-positions of the androgen skeleton.
Topics: Androgens; Androstadienes; Catalysis; Hydrogen; Methane; Oxygen; Rhodium; Silver | 2012 |
Rh-catalyzed intermolecular reactions of cyclic α-diazocarbonyl compounds with selectivity over tertiary C-H bond migration.
Topics: Azo Compounds; Catalysis; Computer Simulation; Cyclopropanes; Hydrogen; Methane; Molecular Conformation; Rhodium; Stereoisomerism | 2012 |
Stereoselective intermolecular C-H amination reactions.
Topics: Acetates; Amination; Amines; Benzylamines; Carbon; Catalysis; Hydrogen; Pargyline; Propylamines; Rhodium; Stereoisomerism | 2012 |
Rhodium(III)-catalyzed intramolecular annulation through C-H activation: total synthesis of (±)-antofine, (±)-septicine, (±)-tylophorine, and rosettacin.
Topics: Alkaloids; Alkynes; Carbon; Catalysis; Cyclization; Heterocyclic Compounds, 4 or More Rings; Hydrogen; Indoles; Indolizines; Isoquinolines; Phenanthrenes; Phenanthrolines; Pyridones; Rhodium; Stereoisomerism | 2012 |
Access to sultams by rhodium(III)-catalyzed directed C-H activation.
Topics: Alkynes; Carbon; Catalysis; Cyclization; Heterocyclic Compounds; Hydrogen; Rhodium; Sulfonamides | 2012 |
The synergistic effect of Rh-Ni catalysts on the highly-efficient dehydrogenation of aqueous hydrazine borane for chemical hydrogen storage.
Topics: Alloys; Boranes; Catalysis; Hydrazines; Hydrogen; Hydrogenation; Nanostructures; Nickel; Particle Size; Rhodium; Surface Properties; Water | 2012 |
Rhodium-catalyzed regioselective amidation of indoles with sulfonyl azides via C-H bond activation.
Topics: Amides; Azides; Carbon; Catalysis; Hydrogen; Indoles; Rhodium; Stereoisomerism; Substrate Specificity | 2012 |
Rhodium(III) and hexabromobenzene-a catalyst system for the cross-dehydrogenative coupling of simple arenes and heterocycles with arenes bearing directing groups.
Topics: Alkenes; Benzamides; Bromobenzenes; Carbon; Catalysis; Hydrogen; Rhodium | 2012 |
Biotinylated Rh(III) complexes in engineered streptavidin for accelerated asymmetric C-H activation.
Topics: Alkenes; Benzamides; Biotinylation; Carbon; Catalysis; Catalytic Domain; Coordination Complexes; Enzyme Activation; Enzymes; Hydrogen; Mutagenesis, Site-Directed; Protein Engineering; Rhodium; Streptavidin; Substrate Specificity | 2012 |
Rhodium complex immobilized on graphene oxide as an efficient and recyclable catalyst for hydrogenation of cyclohexene.
Topics: Adsorption; Catalysis; Cyclohexenes; Graphite; Hydrogen; Hydrogenation; Nanoparticles; Oxides; Recycling; Rhodium | 2013 |
Rhodium(I)-catalyzed enantioselective hydrogenation of substituted acrylic acids with sterically similar β,β-diaryls.
Topics: Acrylates; Catalysis; Combinatorial Chemistry Techniques; Hydrogen; Hydrogen Bonding; Hydrogenation; Ligands; Oxides; Phosphines; Rhodium; Stereoisomerism | 2013 |
Alkyl group versus hydrogen atom transfer from metal alkyls to macrocyclic rhodium complexes.
Topics: Alkenes; Coordination Complexes; Hydrogen; Kinetics; Rhodium | 2013 |
Rhodium-catalyzed synthesis of amides from aldehydes and azides by chelation-assisted C-H bond activation.
Topics: Aldehydes; Amides; Azides; Carbon; Catalysis; Chelating Agents; Cyclopentanes; Hydrogen; Hydrogen-Ion Concentration; Rhodium | 2013 |
Selective intermolecular amination of C-H bonds at tertiary carbon centers.
Topics: Amination; Amines; Carbon; Hydrogen; Rhodium; Stereoisomerism | 2013 |
Chemo- and regioselective homogeneous rhodium-catalyzed hydroamidomethylation of terminal alkenes to N-alkylamides.
Topics: Aldehydes; Alkenes; Amides; Atmosphere; Carbon Monoxide; Catalysis; Hydrogen; Kinetics; Methylation; Oxidation-Reduction; Rhodium; Stereoisomerism; Substrate Specificity | 2013 |
Indole synthesis by rhodium(III)-catalyzed hydrazine-directed C-H activation: redox-neutral and traceless by N-N bond cleavage.
Topics: Carbon; Catalysis; Cyclization; Hydrazines; Hydrogen; Indoles; Nitrogen; Oxidation-Reduction; Rhodium | 2013 |
One-pot synthesis of 3-alkylidenephthalides from benzoic acids by a rhodium-catalyzed ortho-C-H acylation process.
Topics: Acylation; Benzoates; Benzofurans; Carbon; Catalysis; Coordination Complexes; Hydrogen; Rhodium | 2013 |
Solid solution alloy nanoparticles of immiscible Pd and Ru elements neighboring on Rh: changeover of the thermodynamic behavior for hydrogen storage and enhanced CO-oxidizing ability.
Topics: Alloys; Carbon Monoxide; Catalysis; Hydrogen; Microscopy, Electron, Transmission; Nanoparticles; Oxidation-Reduction; Palladium; Rhodium; Ruthenium; Surface Properties; Thermodynamics | 2014 |
Analyzing site selectivity in Rh2(esp)2-catalyzed intermolecular C-H amination reactions.
Topics: Amination; Carbon; Catalysis; Hydrogen; Models, Chemical; Rhodium | 2014 |
Asymmetric hydroformylation catalyzed by RhH(CO)₂[(R,S)-Yanphos]: mechanism and origin of enantioselectivity.
Topics: Aldehydes; Alkenes; Carbon Monoxide; Catalysis; Computer Simulation; Hydrogen; Models, Chemical; Molecular Structure; Oxidation-Reduction; Rhodium; Styrene | 2014 |
Hydride-rhodium(III)-N-heterocyclic carbene catalysts for vinyl-selective H/D exchange: a structure-activity study.
Topics: Catalysis; Coordination Complexes; Crystallography, X-Ray; Deuterium; Heterocyclic Compounds; Hydrogen; Methane; Molecular Conformation; Rhodium; Structure-Activity Relationship; Vinyl Compounds | 2014 |
Demonstration of heterogeneous parahydrogen induced polarization using hyperpolarized agent migration from dissolved Rh(I) complex to gas phase.
Topics: Coordination Complexes; Equipment Design; Gases; Hydrogen; Hydrogenation; Magnetic Resonance Spectroscopy; Norbornanes; Rhodium; Solubility | 2014 |
Rhodium(III)-catalyzed regioselective C2-amidation of indoles with N-(2,4,6-trichlorobenzoyloxy)amides and its synthetic application to the development of a novel potential PPARγ modulator.
Topics: Adipocytes; Adipose Tissue; Amides; Animals; Carbon; Catalysis; Cell Differentiation; Chemistry, Organic; Chlorocebus aethiops; COS Cells; Drug Design; Hydrogen; Indoles; Inhibitory Concentration 50; Molecular Structure; Nitrogen; Oxygen; PPAR gamma; Protein Binding; Rhodium; Rosiglitazone; Thiazolidinediones | 2014 |
High-resolution 3D proton MRI of hyperpolarized gas enabled by parahydrogen and Rh/TiO2 heterogeneous catalyst.
Topics: Catalysis; Gases; Hydrogen; Imaging, Three-Dimensional; Magnetic Resonance Imaging; Magnetic Resonance Spectroscopy; Protons; Rhodium; Titanium | 2014 |
Reaction mediated artificial cell termination: control of vesicle viability using Rh(I)-catalyzed hydrogenation.
Topics: Catalysis; Hydrogen; Lipids; Rhodium | 2014 |
Rhodium(III)-catalyzed C-H activation/[4+3] annulation of N-phenoxyacetamides and α,β-unsaturated aldehydes: an efficient route to 1,2-oxazepines at room temperature.
Topics: Acetamides; Aldehydes; Carbon; Catalysis; Crystallography, X-Ray; Cycloaddition Reaction; Hydrogen; Molecular Conformation; Nitrogen; Oxazepines; Rhodium; Temperature | 2014 |
Rhodium(III)-catalyzed C-H/C-C activation sequence: vinylcyclopropanes as versatile synthons in direct C-H allylation reactions.
Topics: Carbon; Catalysis; Coordination Complexes; Cyclization; Cyclopropanes; Hydrogen; Oxidation-Reduction; Rhodium; Stereoisomerism; Vinyl Compounds | 2015 |
Enantioselective synthesis of (-)-maoecrystal V by enantiodetermining C-H functionalization.
Topics: Antineoplastic Agents; Benzofurans; Carbon; Catalysis; Cell Line, Tumor; Cell Proliferation; Cycloaddition Reaction; Diterpenes; Humans; Hydrogen; Rhodium; Stereoisomerism; Substrate Specificity | 2014 |
Catalytic hydrodechlorination of benzyl chloride promoted by Rh-N-heterocyclic carbene catalysts.
Topics: Benzyl Compounds; Catalysis; Halogenation; Heterocyclic Compounds; Hydrogen; Methane; Models, Molecular; Molecular Conformation; Rhodium; Silanes | 2015 |
Rhodium(III)-catalyzed cyclative capture approach to diverse 1-aminoindoline derivatives at room temperature.
Topics: Alkenes; Carbon; Catalysis; Hydrogen; Indoles; Quantum Theory; Rhodium; Temperature | 2015 |
Concise syntheses of dictyodendrins A and F by a sequential C-H functionalization strategy.
Topics: Carbazoles; Carbon; Catalysis; Chemistry Techniques, Synthetic; Hydrogen; Pyrroles; Rhodium | 2015 |
Multi-site cyclization via initial C-H activation using a rhodium(III) catalyst: rapid assembly of frameworks containing indoles and indolines.
Topics: Carbon; Catalysis; Cyclization; Hydrogen; Indoles; Kinetics; Oxidation-Reduction; Rhodium | 2015 |
Late-stage C-H functionalization of complex alkaloids and drug molecules via intermolecular rhodium-carbenoid insertion.
Topics: Alkaloids; Amines; Biological Products; Carbon; Catalysis; Chemistry, Pharmaceutical; Drug Design; Hydrogen; Magnetic Resonance Spectroscopy; Rhodium; Strychnine | 2015 |
Rhodium(III)-catalyzed C-H activation and intermolecular annulation with terminal alkynes: from indoles to carbazoles.
Topics: Alkynes; Carbazoles; Carbon; Catalysis; Hydrogen; Indoles; Rhodium; Stereoisomerism; Substrate Specificity | 2015 |
Rhodium-catalysed direct C-H allylation of N-sulfonyl ketimines with allyl carbonates.
Topics: Allyl Compounds; Carbon; Carbonates; Catalysis; Hydrogen; Imines; Models, Molecular; Molecular Conformation; Nitriles; Rhodium | 2015 |
Rhodathiaborane reaction cycles driven by C2H4 and H2: synthesis and characterization of [(H)2(PPh3)RhSB8H7(PPh3)] and [(η(2)-C2H4)(PPh3)RhSB8H7(PPh3)].
Topics: Boranes; Boron Compounds; Chemistry Techniques, Synthetic; Ethylenes; Hydrogen; Organometallic Compounds; Rhodium | 2015 |
Cooperative dehydrogenation of N-heterocycles using a carbon nanotube-rhodium nanohybrid.
Topics: Catalysis; Catechols; Heterocyclic Compounds; Hydrogen; Hydrogenation; Metal Nanoparticles; Nanotubes, Carbon; Rhodium | 2015 |
One-pot synthesis of 2,3-disubstituted dihydrobenzofurans and benzofurans via rhodium-catalyzed intramolecular C-H insertion reaction.
Topics: Benzofurans; Carbon; Catalysis; Chemistry Techniques, Synthetic; Hydrogen; Rhodium | 2015 |
Rhodium-catalysed synthesis of multi-substituted silylindenes from aryl alkynes and hydrosilanes via C-H bond activation.
Topics: Alkynes; Carbon; Catalysis; Hydrogen; Indenes; Molecular Structure; Organometallic Compounds; Organosilicon Compounds; Rhodium; Silanes | 2015 |
Rh(III)- or Ir(III)-catalyzed ynone synthesis from aldehydes via chelation-assisted C-H bond activation.
Topics: Aldehydes; Alkynes; Carbon; Catalysis; Chelating Agents; Hydrogen; Iridium; Molecular Structure; Organometallic Compounds; Rhodium | 2015 |
Rhodium(III)-Catalyzed [3+2]/[5+2] Annulation of 4-Aryl 1,2,3-Triazoles with Internal Alkynes through Dual C(sp2)-H Functionalization.
Topics: Alkynes; Azepines; Carbon; Catalysis; Cycloaddition Reaction; Hydrogen; Rhodium; Triazoles | 2015 |
Rhodium(III)-Catalyzed ortho C-H Heteroarylation of (Hetero)aromatic Carboxylic Acids: A Rapid and Concise Access to π-Conjugated Poly-heterocycles.
Topics: Carbon; Carboxylic Acids; Catalysis; Heterocyclic Compounds; Hydrogen; Rhodium; Stereoisomerism | 2015 |
Rhodium(III)-Catalyzed Activation of C(sp3)-H Bonds and Subsequent Intermolecular Amidation at Room Temperature.
Topics: Amides; Carbon; Catalysis; Crystallography, X-Ray; Hydrogen; Molecular Conformation; Rhodium; Temperature | 2015 |
Rh-Catalyzed Construction of Quinolin-2(1H)-ones via C-H Bond Activation of Simple Anilines with CO and Alkynes.
Topics: Alkynes; Aniline Compounds; Carbon; Carbon Monoxide; Catalysis; Hydrogen; Quinolones; Rhodium | 2015 |
Pyridine N-Oxide vs Pyridine Substrates for Rh(III)-Catalyzed Oxidative C-H Bond Functionalization.
Topics: Alkynes; Binding Sites; Carbon; Catalysis; Hydrogen; Kinetics; Models, Molecular; Molecular Conformation; Oxidation-Reduction; Pyridines; Rhodium | 2015 |
Porous frameworks constructed by non-covalent linking of substitution-inert metal complexes.
Topics: Adsorption; Catalytic Domain; Coordination Complexes; Crystallization; Crystallography, X-Ray; Dimerization; Fluorine; Hydrogen; Ligands; Magnetic Resonance Spectroscopy; Metals; Molecular Conformation; Nitrogen; Porosity; Rhodium; Spectroscopy, Fourier Transform Infrared; Temperature; Thermogravimetry; X-Ray Diffraction | 2015 |
Redox-neutral rhodium-catalyzed C-H functionalization of arylamine N-oxides with diazo compounds: primary C(sp(3))-H/C(sp(2))-H activation and oxygen-atom transfer.
Topics: 1-Naphthylamine; Amination; Aniline Compounds; Azo Compounds; Catalysis; Hydrogen; Indoles; Malonates; Mandelic Acids; Models, Molecular; Nitrogen Oxides; Oxidation-Reduction; Rhodium | 2015 |
Mechanism and Mitigation of the Decomposition of an Oxorhenium Complex-Based Heterogeneous Catalyst for Perchlorate Reduction in Water.
Topics: Catalysis; Charcoal; Hydrogen; Kinetics; Metal Nanoparticles; Oxidation-Reduction; Palladium; Perchlorates; Rhenium; Rhodium; Ruthenium; Solubility; Water; Water Pollutants, Chemical; Water Purification | 2015 |
Rhodium-catalysed syn-carboamination of alkenes via a transient directing group.
Topics: Alkenes; Amination; Amines; Carbon; Catalysis; Hydrogen; Models, Chemical; Nitrogen; Oxidation-Reduction; Rhodium | 2015 |
Rh-Catalyzed Intermolecular Reactions of α-Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β-Hydride Migration.
Topics: Alkenes; Catalysis; Cyclization; Diazonium Compounds; Hydrogen; Methane; Molecular Structure; Organometallic Compounds; Rhodium; Stereoisomerism | 2016 |
Rhodium-catalyzed annulation of arenes with alkynes through weak chelation-assisted C-H activation.
Topics: Alkynes; Carbon; Catalysis; Chelating Agents; Hydrogen; Rhodium | 2016 |
Efficient Synthesis of Molecular Precursors for Para-Hydrogen-Induced Polarization of Ethyl Acetate-1-(13) C and Beyond.
Topics: Acetates; Carbon Isotopes; Catalysis; Coordination Complexes; Hydrogen; Isotope Labeling; Magnetic Resonance Spectroscopy; Rhodium | 2016 |
Synthesis of 2-Butanol by Selective Hydrogenolysis of 1,4-Anhydroerythritol over Molybdenum Oxide-Modified Rhodium-Supported Silica.
Topics: Butanols; Chemistry Techniques, Synthetic; Erythritol; Hydrogen; Kinetics; Molybdenum; Oxides; Rhodium; Silicon Dioxide | 2016 |
Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C-H Bonds.
Topics: Carbon; Catalysis; Cyclopropanes; Hydrogen; Rhodium; Silanes; Stereoisomerism | 2016 |
Switching stiction and adhesion of a liquid on a solid.
Topics: Adhesiveness; Animals; Boron Compounds; Electricity; Friction; Hydrogen; Locomotion; Lubrication; Rhodium; Wettability | 2016 |
Hydrogen Production and Storage on a Formic Acid/Bicarbonate Platform using Water-Soluble N-Heterocyclic Carbene Complexes of Late Transition Metals.
Topics: Bicarbonates; Catalysis; Formates; Heterocyclic Compounds; Hot Temperature; Hydrogen; Indium; Kinetics; Methane; Rhodium; Solubility; Water | 2016 |
Integration of Quantum Confinement and Alloy Effect to Modulate Electronic Properties of RhW Nanocrystals for Improved Catalytic Performance toward CO
Topics: Adsorption; Alloys; Carbon Dioxide; Catalysis; Electronics; Hydrogen; Hydrogenation; Methanol; Models, Theoretical; Nanoparticles; Particle Size; Rhodium; Surface Properties; Tungsten | 2017 |
Synthesis of [5,6]-Bicyclic Heterocycles with a Ring-Junction Nitrogen Atom: Rhodium(III)-Catalyzed C-H Functionalization of Alkenyl Azoles.
Topics: Alkynes; Azoles; Bridged Bicyclo Compounds, Heterocyclic; Carbon; Catalysis; Coordination Complexes; Cyclization; Hydrogen; Isomerism; Nitrogen; Rhodium | 2017 |
Alkyne Hydroheteroarylation: Enantioselective Coupling of Indoles and Alkynes via Rh-Hydride Catalysis.
Topics: Alkynes; Catalysis; Hydrogen; Indoles; Rhodium; Stereoisomerism | 2017 |
Ligand Substituents Govern the Efficiency and Mechanistic Path of Hydrogen Production with [Cp*Rh] Catalysts.
Topics: 2,2'-Dipyridyl; Catalysis; Electrochemical Techniques; Energy-Generating Resources; Hydrogen; Ligands; Organometallic Compounds; Rhodium | 2017 |
Site-selective and stereoselective functionalization of non-activated tertiary C-H bonds.
Topics: Biological Products; Carbon; Catalysis; Cytochrome P-450 Enzyme System; Hydrogen; Hydrogen Bonding; Methane; Models, Molecular; Molecular Structure; Rhodium; Steroids; Vitamin E | 2017 |
More Than 12 % Polarization and 20 Minute Lifetime of
Topics: Amines; Catalysis; Choline; Deuterium; Hydrogen; Hydrogenation; Metal Nanoparticles; Nitrogen Isotopes; Rhodium; Water | 2018 |
Triorganoindium Reagents in Rh-Catalyzed C⁻H Activation/C⁻C Cross-Coupling Reactions of 2-Arylpyridines.
Topics: Carbon; Catalysis; Hydrogen; Indium; Organometallic Compounds; Oxidative Coupling; Pyridines; Rhodium | 2018 |
Three-Component Coupling of Aldehydes, Aminopyrazoles, and Sulfoxonium Ylides via Rhodium(III)-Catalyzed Imidoyl C-H Activation: Synthesis of Pyrazolo[1,5- a]pyrimidines.
Topics: Aldehydes; Carbon; Catalysis; Chemistry Techniques, Synthetic; Hydrogen; Pyrazoles; Pyrimidines; Rhodium; Sulfonium Compounds | 2018 |
Asymmetric N-H Insertion Reaction with Chiral Aminoalcohol as Catalytic Core of Cinchona Alkaloids.
Topics: Amino Alcohols; Benzyl Alcohols; Catalysis; Cinchona Alkaloids; Coordination Complexes; Hydrogen; Nitrogen; Rhodium; Stereoisomerism | 2019 |
Meeting organometallic chemistry with drug discovery: CH activation enabled discovery of a new ring system of 12H-Indazolo[2,1-a]cinnolin-12-ones with anti-proliferation activity.
Topics: Alkylation; Antineoplastic Agents; Apoptosis; Carbon; Caspase 3; Catalysis; Cell Cycle Checkpoints; Cell Line, Tumor; Cell Survival; Drug Design; Heterocyclic Compounds, 2-Ring; Humans; Hydrogen; Organometallic Compounds; Rhodium; Ruthenium Compounds; Up-Regulation | 2020 |
A site-selective amination catalyst discriminates between nearly identical C-H bonds of unsymmetrical disubstituted alkenes.
Topics: Alkenes; Amination; Carbon; Catalysis; Coordination Complexes; Hydrogen; Rhodium; Stereoisomerism; Thermodynamics | 2020 |
Incorporation of a Cp*Rh(III)-dithiophosphate Cofactor with Latent Activity into a Protein Scaffold Generates a Biohybrid Catalyst Promoting C(sp
Topics: Biomimetic Materials; Carbon; Catalysis; Coordination Complexes; Hydrogen; Oximes; Phosphates; Proteins; Rhodium; Silver | 2020 |
Enantioselective Addition of α-Nitroesters to Alkynes.
Topics: Alkynes; Amino Acids; Catalysis; Coordination Complexes; Esters; Hydrogen; Rhodium; Stereoisomerism | 2021 |
Enantioselective hydrogenation of cyclic tetrasubstituted-olefinic dehydroamino acid derivatives.
Topics: Amino Acids; Catalysis; Coordination Complexes; Cycloparaffins; Hot Temperature; Hydrogen; Hydrogenation; Kinetics; Ligands; Molecular Structure; Pressure; Rhodium; Stereoisomerism | 2021 |
Mechanistically Guided Workflow for Relating Complex Reactive Site Topologies to Catalyst Performance in C-H Functionalization Reactions.
Topics: Carbon; Catalysis; Coordination Complexes; Hydrogen; Kinetics; Methane; Rhodium; Stereoisomerism; Thermodynamics | 2022 |
Catalytic Activation of Unstrained C(Aryl)-C(Alkyl) Bonds in 2,2'-Methylenediphenols.
Topics: Benzhydryl Compounds; Catalysis; Coordination Complexes; Hydrogen; Models, Chemical; Molecular Structure; Oxidation-Reduction; Phenols; Rhodium | 2022 |
Hydrogen evolution-enabled rhodaelectro-catalyzed [4+2] annulations of purines and 7-deazapurines with alkynes.
Topics: Alkynes; Catalysis; Hydrogen; Purines; Rhodium | 2022 |