hectorite has been researched along with 1-10-phenanthroline* in 1 studies
1 other study(ies) available for hectorite and 1-10-phenanthroline
Article | Year |
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Highly enantioselective asymmetric autocatalysis using chiral ruthenium complex-ion-exchanged synthetic hectorite as a chiral initiator.
The synthetic hectorite containing intercalated chiral Delta- and Lambda-tris(1,10-phenanthroline)ruthenium(II) ions acts as a heterogeneous chiral catalyst in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde to afford, in combination with asymmetric autocatalytic amplification of enantiomeric excess, 5-pyrimidyl alkanol with high enantiomeric excess. Topics: Catalysis; Ion Exchange; Molecular Structure; Organometallic Compounds; Phenanthrolines; Ruthenium; Silicates; Stereoisomerism | 2009 |