harman has been researched along with quinoline* in 1 studies
1 other study(ies) available for harman and quinoline
Article | Year |
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A spectroscopic study of the hydrogen bonding and pi-pi stacking interactions of harmane with quinoline.
A spectroscopic (UV-vis, Fourier transform IR, steady state, and time-resolved fluorescence) study of the interactions of the ground and excited singlet states of harmane (1-methyl-9H-pyrido/3,4-b/indole) with quinoline has been carried out in cyclohexane, toluene, and buffered pH=8.7 aqueous solutions. To analyze how the number of rings in the substrate influences these interactions, pyridine and phenanthridine have also been included in this study. In cyclohexane and toluene 1:1 stoichiometric hydrogen-bonded complexes are formed in both the ground and the excited singlet states. As the number of rings of the benzopyridines and the solvent polarity increase hydrogen-bonding interactions weaken and pi-pi van der Waals interactions become apparent. Topics: Buffers; Cyclohexanes; Harmine; Hydrogen Bonding; Hydrogen-Ion Concentration; Kinetics; Models, Chemical; Molecular Structure; Quinolines; Spectrophotometry; Spectroscopy, Fourier Transform Infrared; Toluene | 1998 |