guanacastepene and 1-4-cyclohexadiene

guanacastepene has been researched along with 1-4-cyclohexadiene* in 1 studies

Other Studies

1 other study(ies) available for guanacastepene and 1-4-cyclohexadiene

Article	Year
Synthesis of the 5-7-6 core of guanacastepenes. Construction of C8 quaternary carbon via the inversion of stereochemistry. Organic letters, 2002, Oct-31, Volume: 4, Issue:22 [formula: see text] An efficient and unique route to the 5-7-6 core of guanacatepene A (1) is described. The installation of the desired stereochemistry at the C8 position was achieved via the desymmetrization of the cyclohexadienone by reductive ring closure of the seven-membered ring. That the closure of the seven-membered ring produced only the desired isomer is hypothesized to be a result of the more stable trans relationship between the C8 and C11 methyl groups. Topics: Anti-Bacterial Agents; Cyclization; Cyclohexanes; Cyclohexenes; Diterpenes; Stereoisomerism	2002

Article

Year

Synthesis of the 5-7-6 core of guanacastepenes. Construction of C8 quaternary carbon via the inversion of stereochemistry.

Organic letters, 2002, Oct-31, Volume: 4, Issue:22

[formula: see text] An efficient and unique route to the 5-7-6 core of guanacatepene A (1) is described. The installation of the desired stereochemistry at the C8 position was achieved via the desymmetrization of the cyclohexadienone by reductive ring closure of the seven-membered ring. That the closure of the seven-membered ring produced only the desired isomer is hypothesized to be a result of the more stable trans relationship between the C8 and C11 methyl groups.

Topics: Anti-Bacterial Agents; Cyclization; Cyclohexanes; Cyclohexenes; Diterpenes; Stereoisomerism

2002