grandiflorenic-acid and o-iodoxybenzoic-acid

grandiflorenic-acid has been researched along with o-iodoxybenzoic-acid* in 1 studies

Other Studies

1 other study(ies) available for grandiflorenic-acid and o-iodoxybenzoic-acid

ArticleYear
Efficient access to orthoquinols and their [4 + 2] cyclodimers via SIBX-mediated hydroxylative phenol dearomatization.
    The Journal of organic chemistry, 2007, Aug-03, Volume: 72, Issue:16

    SIBX, the nonexplosive formulation of the lambda5-iodane 2-iodoxybenzioc acid (IBX), safely and efficiently mediates the hydroxylative dearomatization of various 2-alkylphenols and napthols into orthoquinols or their [4 + 2] cyclodimers. Reactions are typically run at room temperature using SIBX as a suspension in THF. Using these conditions, natural products such as the cyclodimer of the terpene carvacrol and, for the first time, the shikimate-derived (+/-)-grandifloracin were prepared in one step from their respective phenolic precursor.

    Topics: Chemistry, Organic; Chromatography; Dimerization; Diterpenes; Hydroquinones; Hydroxylation; Iodobenzenes; Iodobenzoates; Models, Chemical; Molecular Structure; Naphthols; Phenols; Stereoisomerism

2007