gracilioether-f and ketene

gracilioether-f has been researched along with ketene* in 1 studies

Other Studies

1 other study(ies) available for gracilioether-f and ketene

Article	Year
Total synthesis of gracilioether F: development and application of lewis Acid promoted ketene-alkene [2+2] cycloadditions and late-stage C-H oxidation. Angewandte Chemie (International ed. in English), 2014, Dec-22, Volume: 53, Issue:52 The first synthesis of gracilioether F, a polyketide natural product with an unusual tricyclic core and five contiguous stereocenters, is described. Key steps of the synthesis include a Lewis acid promoted ketene-alkene [2+2] cycloaddition and a late-stage carboxylic acid directed C(sp(3) )H oxidation. The synthesis requires only eight steps from norbornadiene. Topics: Alkenes; Carbon; Cycloaddition Reaction; Ethylenes; Heterocyclic Compounds, 3-Ring; Hydrogen; Ketones; Lewis Acids; Oxidation-Reduction	2014

Article

Year

Total synthesis of gracilioether F: development and application of lewis Acid promoted ketene-alkene [2+2] cycloadditions and late-stage C-H oxidation.

Angewandte Chemie (International ed. in English), 2014, Dec-22, Volume: 53, Issue:52

The first synthesis of gracilioether F, a polyketide natural product with an unusual tricyclic core and five contiguous stereocenters, is described. Key steps of the synthesis include a Lewis acid promoted ketene-alkene [2+2] cycloaddition and a late-stage carboxylic acid directed C(sp(3) )H oxidation. The synthesis requires only eight steps from norbornadiene.

Topics: Alkenes; Carbon; Cycloaddition Reaction; Ethylenes; Heterocyclic Compounds, 3-Ring; Hydrogen; Ketones; Lewis Acids; Oxidation-Reduction

2014