glyoxamide and mandelamide

glyoxamide has been researched along with mandelamide* in 1 studies

Other Studies

1 other study(ies) available for glyoxamide and mandelamide

Article	Year
Anisotropic and hydrogen bonding effects in phenylglyoxamides and mandelamides: theoretical and NMR conformational evaluation. Magnetic resonance in chemistry : MRC, 2008, Volume: 46, Issue:5 Interesting anisotropic effects were observed for phenylglyoxamides and their respective mandelamides. Such effects were observed in experimental (1)H and (13)C NMR (in CDCl(3), CD(3)OD, and DMSO-d(6) solvents) and in some cases with good correlation to theoretical (1)H and (13)C NMR DFT-GIAO (B3LYP/6-311++G*//B3LYP/6-31G) calculations. A systematic conformational analysis of these compounds was performed in a two-step methodology, using PM3 and DFT (B3LYP/6-31G*) calculations; with good accomplishment and computational time economy. It was observed that intramolecular hydrogen bonding plays a significant role in the conformation of such compounds. Finally, a geminal nonequivalence of an N-CH(2) moiety, in one of the alkyl side chain (R1 = R2), was found for the tertiary mandelamides studied. Topics: Anisotropy; Computer Simulation; Hydrogen; Hydrogen Bonding; Magnetic Resonance Spectroscopy; Mandelic Acids; Models, Chemical; Models, Molecular; Molecular Conformation; Sulfonylurea Compounds	2008

Article

Year

Anisotropic and hydrogen bonding effects in phenylglyoxamides and mandelamides: theoretical and NMR conformational evaluation.

Magnetic resonance in chemistry : MRC, 2008, Volume: 46, Issue:5

Interesting anisotropic effects were observed for phenylglyoxamides and their respective mandelamides. Such effects were observed in experimental (1)H and (13)C NMR (in CDCl(3), CD(3)OD, and DMSO-d(6) solvents) and in some cases with good correlation to theoretical (1)H and (13)C NMR DFT-GIAO (B3LYP/6-311++G**//B3LYP/6-31G*) calculations. A systematic conformational analysis of these compounds was performed in a two-step methodology, using PM3 and DFT (B3LYP/6-31G*) calculations; with good accomplishment and computational time economy. It was observed that intramolecular hydrogen bonding plays a significant role in the conformation of such compounds. Finally, a geminal nonequivalence of an N-CH(2) moiety, in one of the alkyl side chain (R1 = R2), was found for the tertiary mandelamides studied.

Topics: Anisotropy; Computer Simulation; Hydrogen; Hydrogen Bonding; Magnetic Resonance Spectroscopy; Mandelic Acids; Models, Chemical; Models, Molecular; Molecular Conformation; Sulfonylurea Compounds

2008