glyoxamide has been researched along with carbene* in 1 studies
1 other study(ies) available for glyoxamide and carbene
| Article | Year |
|---|---|
Catalytic asymmetric intermolecular Stetter reaction of glyoxamides with alkylidenemalonates.
An asymmetric intermolecular Stetter reaction of glyoxamide and alkylidenemalonates has been developed. Catalyzed by a novel N-heterocyclic carbene, the Stetter adducts are formed in good yield and excellent enantioselectivity. The presence of a sensitive epimerizable stereocenter is tolerated under these mildly basic reaction conditions if a bulky amine base is used. The products may be further elaborated to provide synthetically useful intermediates. Topics: Alkadienes; Amides; Catalysis; Malonates; Methane; Molecular Structure; Phenylalanine; Stereoisomerism; Sulfonylurea Compounds | 2008 |