geranyl-pyrophosphate and coumarin

geranyl-pyrophosphate has been researched along with coumarin* in 1 studies

Other Studies

1 other study(ies) available for geranyl-pyrophosphate and coumarin

ArticleYear
A fluorescence sensor for detection of geranyl pyrophosphate by the chemo-ensemble method.
    The Journal of organic chemistry, 2009, Jan-16, Volume: 74, Issue:2

    Hexaamide receptor 4 and coumarin phosphate 5 form an ensemble for effective sensing of geranyl pyrophosphate (GPP). Fluorescence resonance energy transfer in the 4 + 5 ensemble diminishes when 5 is replaced by GPP. Receptor 4 binds selectively with GPP over other anions, including fatty acids. The 4-GPP complex in 1:1 stoichiometry is inferred by NMR and fluorescence titrations. Receptor 4 contains a pseudotetrahedral cleft to accommodate GPP via multiple hydrogen bonds, and the two aliphatic chains exert additional hydrophobic interactions.

    Topics: Amides; Calibration; Coumarins; Fluorescence; Fluorescent Dyes; Magnetic Resonance Spectroscopy; Polyisoprenyl Phosphates; Titrimetry

2009