geranyl-acetate and citronellyl-acetate

This study focused on the impact of esters on the perception of floral aroma in rose essential oil. Various aromatic reconstitutions were prepared, consisting of 10 alcohols and 9 esters, all the concentrations found in rose essential oil. Sensory analysis by the triangular tests revealed the interesting behavior of certain compounds among the 9 esters following their addition or omission. The results tend to highlight the important role of ethyl octanoate, ethyl tetradecanoate, citronellyl acetate, geranyl acetate, and 2-phenethyl acetate of esters in rose essential oil. The "olfactory threshold" (OT) of the 5 esters, the floral reconstitution and the mixtures of ester and floral reconstitution were evaluated in alkanes solution. Through the Feller's additive model analysis, it was found that the presence of ethyl octanoate, ethyl tetradecanoate, and citronellyl acetate led to a significant in decrease the OT of the mixtures, whereas geranyl acetate raised the OT. The floral reconstitution in alkanes solution was supplemented with the 5 esters at high, medium, and low concentration, then analyzed by quantitative descriptive analysis. It was revealed that ethyl octanoate, ethyl tetradecanoate, and citronellyl acetate adding overall aroma, and geranyl acetate masking the overall aroma perception in a model floral mixture. Sensory profiles highlighted changes in the perception of aroma nuances in the presence of the 5 esters, with specific perceptive interactions, and reported on the graph based on two parameters [σ = f(τ)]. This paper provided a reference for the flavourists.

Topics: Acetates; Acyclic Monoterpenes; Adolescent; Adult; Caprylates; Esters; Female; Humans; Male; Monoterpenes; Odorants; Oils, Volatile; Phenylethyl Alcohol; Plant Extracts; Rosa; Solutions; Taste; Young Adult

This study was aimed at assessing the fumigant toxicity of 14 essential oil constituents from lemon eucalyptus, Eucalyptus citriodora Hook, and another ten known compounds to females of acaricide-susceptible, chlorfenapyr-resistant, fenpropathrin-resistant, pyridaben-resistant and abamectin-resistant strains of Tetranychus urticae Koch.. Menthol (LC(50) , 12.9 µg cm(-3) ) was the most toxic compound, followed by citronellyl acetate (16.8 µg cm(-3) ), against the susceptible females. High toxicity was also produced by β-citronellol, citral, geranyl acetate and eugenol (LC(50) , 21.7-24.6 µg cm(-3) ). The fumigant toxicity of these compounds was almost identical against females from either of the susceptible and resistant strains, indicating that the compounds and acaricides do not share a common mode of action or elicit cross-resistance.. Global efforts to reduce the level of highly toxic synthetic acaricides in the agricultural environment justify further studies on materials derived from lemon eucalyptus oil, particularly menthol and citronellyl acetate, as potential acaricides for the control of acaricide-resistant T. urticae as fumigants with contact action.

Topics: Acaricides; Acetates; Acyclic Monoterpenes; Animals; Eucalyptus; Eugenol; Female; Fumigation; Gas Chromatography-Mass Spectrometry; Insecticide Resistance; Menthol; Monoterpenes; Plant Oils; Terpenes; Tetranychidae; Toxicity Tests

Topics: Acetates; Acyclic Monoterpenes; Biotransformation; Chromatography, Gas; Magnetic Resonance Spectroscopy; Mass Spectrometry; Monoterpenes; Pseudomonas; Spectrophotometry, Infrared; Terpenes