gamma-rubromycin and heliquinomycin

gamma-rubromycin has been researched along with heliquinomycin* in 1 studies

Other Studies

1 other study(ies) available for gamma-rubromycin and heliquinomycin

Article	Year
Synthesis of bisbenzannulated spiroketals-model studies for a modular approach to rubromycins. Organic letters, 2006, Oct-12, Volume: 8, Issue:21 [reaction: see text] A highly flexible synthesis of bisbenzannulated spiroketals is described with additions of lithiated methoxyallene to aryl aldehydes and Heck reactions as key steps. Subsequent hydrogenations and ketalizations afforded the desired spiroketals in good yields and with predominating trans-configuration. With model compound 30, already bearing the fully substituted naphthyl core of rubromycins, the ketalization proceeded efficiently providing the expected product 31 and the isopropoxy compound 32. Both products are advanced model compounds of heliquinomycin. Topics: Benzoquinones; Models, Molecular; Molecular Structure; Naphthalenes; Quinones; Spiro Compounds; Stereoisomerism	2006

Article

Year

Synthesis of bisbenzannulated spiroketals-model studies for a modular approach to rubromycins.

Organic letters, 2006, Oct-12, Volume: 8, Issue:21

[reaction: see text] A highly flexible synthesis of bisbenzannulated spiroketals is described with additions of lithiated methoxyallene to aryl aldehydes and Heck reactions as key steps. Subsequent hydrogenations and ketalizations afforded the desired spiroketals in good yields and with predominating trans-configuration. With model compound 30, already bearing the fully substituted naphthyl core of rubromycins, the ketalization proceeded efficiently providing the expected product 31 and the isopropoxy compound 32. Both products are advanced model compounds of heliquinomycin.

Topics: Benzoquinones; Models, Molecular; Molecular Structure; Naphthalenes; Quinones; Spiro Compounds; Stereoisomerism

2006