gamma-cyclodextrin has been researched along with methylglucoside* in 1 studies
1 other study(ies) available for gamma-cyclodextrin and methylglucoside
Article | Year |
---|---|
Migration of secondary tert-butyldimethylsilyl groups in cyclomalto-heptaose and -octaose derivatives.
When 2,6-di-O-tert-butyldimethylsilylated cyclomalto-oligosaccharides (cyclodextrins) are treated with allyl or methyl iodide and NaH in dry tetrahydrofuran, O-2-->O-3 migration of the secondary 2-O-tert-butyldimethylsilyl groups occurs, leading to 2-O-alk(en)yl-3,6-di-O-tert-butyldimethylsilyl-cyclodextrin derivatives. The detection and identification of the reaction step during which migration occurred is described and possible mechanisms of migration are discussed. Topics: Acetylation; beta-Cyclodextrins; Carbohydrate Sequence; Cyclodextrins; gamma-Cyclodextrins; Magnetic Resonance Spectroscopy; Methylglucosides; Molecular Sequence Data; Molecular Structure; Organosilicon Compounds | 1996 |