fusicoccin and cyclopentenone

fusicoccin has been researched along with cyclopentenone* in 1 studies

Other Studies

1 other study(ies) available for fusicoccin and cyclopentenone

Article	Year
Enantioselective synthesis of the C10-C20 fragment of fusicoccin A. The Journal of organic chemistry, 2011, Aug-19, Volume: 76, Issue:16 A synthesis of the fully protected C-ring fragment of the tricyclic diterpene fusicoccin A is reported. The desired cyclopentenyl halides 5a,b are obtained in a total of nine steps. Key transformations of the synthesis sequence are a nonconventional Cr-catalyzed allylic oxidation of a protected intermediate cylcopentenone, a diastereoselective addition of a propenyl Grignard/CeCl(3) reagent to the unmasked cyclopentenone, and an asymmetric hydroboration of the isopropenyl substituent. The protected and suitably functionalized C-ring fragment paves the way to explore further the total synthesis of fusicoccin A. Topics: Catalysis; Cyclopentanes; Diterpenes; Glycosides; Molecular Structure; Oxidation-Reduction; Stereoisomerism	2011

Article

Year

Enantioselective synthesis of the C10-C20 fragment of fusicoccin A.

The Journal of organic chemistry, 2011, Aug-19, Volume: 76, Issue:16

A synthesis of the fully protected C-ring fragment of the tricyclic diterpene fusicoccin A is reported. The desired cyclopentenyl halides 5a,b are obtained in a total of nine steps. Key transformations of the synthesis sequence are a nonconventional Cr-catalyzed allylic oxidation of a protected intermediate cylcopentenone, a diastereoselective addition of a propenyl Grignard/CeCl(3) reagent to the unmasked cyclopentenone, and an asymmetric hydroboration of the isopropenyl substituent. The protected and suitably functionalized C-ring fragment paves the way to explore further the total synthesis of fusicoccin A.

Topics: Catalysis; Cyclopentanes; Diterpenes; Glycosides; Molecular Structure; Oxidation-Reduction; Stereoisomerism

2011