fumaronitrile and carbene

fumaronitrile has been researched along with carbene* in 1 studies

Other Studies

1 other study(ies) available for fumaronitrile and carbene

Article	Year
2H-Azirines from a concerted addition of alkylcarbenes to nitrile groups. Organic letters, 2010, May-21, Volume: 12, Issue:10 Photolysis of aziadamantanes in the presence of fumaronitrile (FN) unexpectedly afforded conjugated 2H-azirines resulting from addition of the carbene to the CN triple bond. This represents the first example of a direct azirine formation starting from an alkylcarbene for which a concerted pathway is postulated. The novel outcome of the reaction is favored by the prior formation of a carbene-alkene complex, a type of adduct that only recently has been described. Topics: Alkenes; Azirines; Crystallography, X-Ray; Fumarates; Methane; Models, Molecular; Molecular Conformation; Photolysis; Stereoisomerism	2010

Article

Year

2H-Azirines from a concerted addition of alkylcarbenes to nitrile groups.

Organic letters, 2010, May-21, Volume: 12, Issue:10

Photolysis of aziadamantanes in the presence of fumaronitrile (FN) unexpectedly afforded conjugated 2H-azirines resulting from addition of the carbene to the CN triple bond. This represents the first example of a direct azirine formation starting from an alkylcarbene for which a concerted pathway is postulated. The novel outcome of the reaction is favored by the prior formation of a carbene-alkene complex, a type of adduct that only recently has been described.

Topics: Alkenes; Azirines; Crystallography, X-Ray; Fumarates; Methane; Models, Molecular; Molecular Conformation; Photolysis; Stereoisomerism

2010